Calculations of S--P transition energies and oscillator strengths in few-electron atoms and ions

ORAL

Abstract

First-principle calculations of transition energies in atoms with accuracy that matches high-resolution spectroscopic measurements is a challenging task. For few-electron atoms (n=2-6), however, this can be done within the framework of the variational method augmented with the use of all-particle explicitly correlated Gaussians (ECGs) and the perturbation theory for treatment of leading relativistic and quantum electrodynamics effects. In this talk I will consider several low-lying S and P states of lithium, beryllium, and carbon ion and demonstrate the current capabilities of the approach. I will also talk about the calculations of dipole moments and oscillator strengths corresponding to S--P transitions.

*This work has been supported by Nazarbayev University FDCRG grant 021220FD3651, and the National Science Foundation grant 1856702.

Publication: [1] S. Nasiri, L. Adamowicz, and S. Bubin, Benchmark calculations of the energy spectra and oscillator strengths of the beryllium atom, J. Phys. Chem. Ref. Data (accepted for publication, in press)
[2] S. Nasiri, S. Bubin, and L. Adamowicz, Oscillator strengths and interstate transition rates in Li atom (in preparation)
[3] S. Nasiri, L. Adamowicz, and S. Bubin, Energy levels and oscillator strengths of the S and P states of C II (planned)

Presenters

  • Sergiy Bubin

    • Nazarbayev University

Authors

  • Sergiy Bubin

    • Nazarbayev University
  • Saeed Nasiri

    • Nazarbaev University
  • Ludwik Adamowicz

    • University of Arizona