Calculation of the dispersion interaction between two atoms

POSTER

Abstract

A general procedure for systematically evaluating the long range interaction between two hetero-nuclear atoms in arbitrary states is outlined. The $C_6$, $C_8$ and $C_{10}$ dispersion coefficients for the excited states of a number of alkali and alkaline atoms interacting with H and He are evaluated. One useful result concerns the lowest order $C_6$ coefficient for a pair of hetero-nuclear atoms. This can always be written in terms of sum rules only involving the oscillator strength. In addition, the coefficients for the long-range interaction between two homo-nuclear lithium atoms in a variety of excited states are presented.

Authors

  • J.-Y. Zhang

    Faculty of Technology, Charles Darwin University, Darwin NT 0909, Australia

  • Jim Mitroy

    Faculty of Technology, Charles Darwin University, Faculty of Technology, Charles Darwin University, Darwin NT 0909, Australia

  • Michael W.J. Bromley

    Department of Physics, San Diego State University, Department of Physics, San Diego State University, San Diego, CA 92182 USA