Cold Chemical Reactions of CaH and Li

ORAL

Abstract

We have observed cold chemical reactions between ground-state molecular CaH ($^2\Sigma$) and atomic Li ($^2S$) at cryogenic temperatures. The molecules and atoms are created by laser ablation of CaH$_2$ and Li targets, respectively, and cooled by buffer-gas cooling. The densities of the reactants are continuously monitored via laser absorption spectroscopy, and a reaction rate coefficient of $10^{-11}$~cm$^3$~s$^{-1}$ is observed for unpolarized reactants. Progress towards controlling the reaction through polarization of the electron spins will be presented.

Authors

  • Vijay Singh

    University of Nevada

  • Kyle Hardman

    University of Nevada

  • Mei-Ju Lu

    University of Nevada

  • Aja Ellis

    University of Nevada

  • Muir Morrison

    University of Nevada, University of Nevada, Reno

  • Jonathan Weinstein

    University of Nevada