Molecule-molecule hyperfine Feshbach resonances

ORAL

Abstract

Magnetic Feshbach scattering resonances play a central role in experimental research of atomic gases at ultracold temperatures. A major thrust of current research is to create an ultracold gas of diatomic alkali-metal molecules in the ground rovibrational state of the ground electronic $^1\Sigma$ state. Can ultracold $^1\Sigma$ molecules be controlled by means of magnetic Feshbach resonances? Unlike alkali metal atoms, $^1\Sigma$ diatomic molecules have no unpaired electrons. The response of $^1\Sigma$ molecules to an external magnetic field is determined entirely by the spin structure of the atomic nuclei. We present the first calculations of molecule-molecule collisions for $^1\Sigma$ molecules in a magnetic field. In particular, we calculate the rates of hyperfine relaxation in molecule - molecule collisions and explore the possibility of tuning magnetic Feshbach resonances in an ultracold gas of $^{87}$Rb$^{133}$Cs(X$^1\Sigma^+$) molecules.

Authors

  • Alisdair Wallis

    University of British Columbia

  • Roman V. Krems

    University of British Columbia