Chemical Reactions of Li and CaH at 1 Kelvin
ORAL
Abstract
Using cryogenic helium buffer-gas cooling, we have prepared dense samples of atomic lithium and molecular calcium monohydride at temperatures as low as 1 Kelvin. We have measured the Li~+~CaH~$\rightarrow$~LiH~+~Ca chemical reaction, observed in both the accelerated disappearance of CaH and in the appearance of the LiH molecule. For unpolarized reactants, we have measured a reaction rate coefficient of $3.6\times10^{-10}$~cm$^3$~s$^{-1}$, with an uncertainty of a factor of 2. The methods of reaction rate measurement and detection of LiH molecules will be presented.
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Authors
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Vijay Singh
University of Nevada
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Kyle S. Hardman
University of Nevada
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Naima Tariq
University of Nevada
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Mei-Ju Lu
University of Nevada
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Aja A. Ellis
University of Nevada
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Muir Morrison
University of Nevada, University of Nevada, Reno
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Jonathan D. Weinstein
University of Nevada, Physics Department, University of Nevada