Non-reactive collisions of sodium and silver atoms with nitrogen molecules

We present a quantal study of elastic and rotationally inelastic collisions of Na and Ag with N$_2$ for energies between 0.1 and 5000 cm$^{-1}$. We obtain the two-dimensional potential energy surface of the ground state of the NaN$_2$ and AgN$_2$ complexes using CCSD(T) methods with the nitrogen molecule frozen at its equilibrium geometry. Using these potentials, we compute the rotationally elastic and inelastic scattering, differential, and momentum transfer cross sections for several initial rotational levels using the close-coupling approach. We also investigate the temperature dependence of the rates corresponding to these collisions. We discuss the importance of sodium-nitrogen collisions in the study of laser guide stars as well as the possibility of substituting Ag for Na in experiments by comparing the cross sections and rates for both systems.