Properties of R$=$2 rotationally excited H$_{2}^{+}$ from fine structure measurements of high-L Rydberg states of H$_{2}$ using novel techniques

Measurement of the fine structure pattern of high-angular momentum Rydberg states provides information about the basic properties of the ion core, such as the Quadrupole moment and polarizability. A novel approach to the detection techniques of Resonant Excitation Stark Ionization Spectroscopy (RESIS) allowed the first measurements of the higher rotational levels of H$_{2}$ that were previously unattainable due to their fast autoionization rates. RESIS uses a Doppler-tuned CO$_{2}$ laser to resonantly excite transitions in a fast molecular beam, which are detected by Stark ionization. Reported here are the experimental details and results along with the analysis of the fine structure measurements of the high-L Rydberg states of the rotationally excited (R$=$2) ground vibrational level of molecular hydrogen. This determines the Quadrupole moment and scalar and tensor dipole polarizabilities of (v$=$0,R$=$2) H$_{2}^{+}$.