Precise measurements of $^{203}$Tl and $^{205}$Tl excited state hyperfine splittings and isotope shifts using two-step vapor cell spectroscopy

POSTER

Abstract

We have undertaken a series of high-precision atomic structure measurement in thallium to test ongoing \emph{ab initio} atomic structure calculations of relevance to symmetry violation experiments in this element. We have recently completed a two-color, two-step spectroscopy experiment to measure of $7P_{1/2}$ hyperfine structure and isotope shift using a heated thallium vapor cell. One laser, locked to the thallium $6P_{1/2}\rightarrow7S_{1/2}$ 378 nm transition excites both naturally-occurring stable isotopes to an intermediate state. A second laser at 1301 nm overlaps the UV beam within the thallium vapor cell in both a co-propagating and counter-propagating configuration. Analysis of subsequent Doppler-free IR absorption spectra of the $7S_{1/2}\rightarrow7P_{1/2}$ transition allows us to extract both hyperfine and isotope shift information for this excited state. Frequency modulation of the IR beam provides convenient \emph{in situ} calibration method for the splittings. Our results significantly disagree with older measurements of these intervals. We have currently substituted a new red diode laser system (671 nm) in place of the infrared laser and are studying the thallium 8p$_{1/2}$ state hyperfine structure.

Authors

  • Protik Majumder

    Physics Dept., Williams College

  • Gabrielle Vukasin

    Physics Dept., Williams College

  • David Kealhofer

    Physics Dept., Williams College

  • Gambhir Ranjit

    Physics Dept., Williams College, University of Nevada, Reno, The University of Nevada, Reno