Quantum Reactive Scattering of Ultracold K+KRb Reaction: Universality and Chaotic Dynamics

ORAL

Abstract

A fundamental question in the study of chemical reactions is how reactions proceed at a collision energy close to absolute zero. This question is no longer hypothetical: quantum degenerate gases of atoms and molecules can now be created at temperatures lower than a few tens of nanoKelvin. In this talk, we discuss the benchmark ultracold reaction between, the most-celebrated ultracold molecule, KRb and K. We report numerically exact quantum-mechanical calculations of the K+KRb reaction on an accurate ab initio ground state potential energy surface of the K$_2$Rb system and compare our results with available experimental data and predictions of universal models. The role of non-additive three-body contributions to the interaction potential is examined and is found to be small for the total reaction rates. However, the rotationally resolved rate coefficients are shown to be sensitive to the short-range interaction potential and follow a Poissonian distribution.

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Authors

  • James F. E. Croft

    University of Nevada, Las Vegas, University of Nevada, Las Vegas, NV 89154

  • Constantinos Makrides

    JQI and NIST, JQI and NIST, Giathersburg, MD, University of Maryland Department of Physics, Joint Quantum Institute, and National Institute of Standards and Technology, Gaithersburg, MD

  • M. Li

    Temple University, Temple University, Philadelphia, PA 19122

  • A. Petrov

    Temple University, Temple University, Philadelphia, PA 19122

  • Brian K. Kendrick

    Los Alamos National Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, Los Alamos Natl Lab, Theoretical Division (T-1, MS B221), Los Alamos National Laboratory, Los Alamos, NM 87545

  • Balakrishnan Naduvalath

    University of Nevada, Las Vegas, University of Nevada, Las Vegas, NV 89154

  • S. Kotochigova

    Temple University, Temple University, Philadelphia, PA 19122