Precision proton-deuteron mass ratio from cyclotron frequency measurements of H$_{2}^{+}$ and D$^{+}$ with H$_{2}^{+}$ in the vibrational ground-state
ORAL
Abstract
Precision measurements of the CFR (cyclotron frequency ratio) of H$_{2}^{+}$ to D$^{+}$ provide an effective means to determine the mass ratio of the proton and deuteron $m_{p}/m_{d}$. Comparison of ions of nearly equal mass results in a large reduction in systematic errors. When the H$_{2}^{+}$ is produced by electron-impact ionization of H$_{2}$ this process is made more complicated because the H$_{2}^{+}$ can be formed in one of 20 vibrational levels, which significantly affects its mass. For instance, the energy difference between $v=1$ and $v=0$ ($J= 0$) corresponds to a fractional change in mass of 1.45 x 10$^{-10}$. However, since our CFR resolution is sufficient to resolve this difference, we can identify the ground vibrational level. In addition, we can accelerate the decay from excited vibrational levels to the ground level by means of Stark-quenching, by placing the H$_{2}^{+}$ in a large cyclotron orbit. The status of our measurements and study of systematics will be presented.
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Authors
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David J Fink
Florida State University
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Edmund G Myers
Florida State University