Atomic data for low temperature mid-Z elements for lithography applications

ORAL

Abstract

Strong emission from plasmas of mid-Z elements, such as tin and xenon, in the 11-14 nm wavelength has long been acknowledged as a powerful source of EUV light with significant applications for lithography. We have performed investigations into the complex atomic structure of relevant ion states (from 5 times ionized to 20 times ionized) to model the low temperature (\textless 50 eV) opacity in Xe. It is known that full configuration-interaction (CI) is required to properly describe the strong mixing between the various n$=$4 subshells that give rise to $\Delta $n$=$0 transitions. We find that this technique results in transition energies within 1{\%} of experimental values. Detailed comparisons will be presented. In opacity calculations, large numbers of configurations are necessary to ensure a converged partition function. Full CI calculations for many configurations quickly becomes computationally prohibitive. Instead, we use a model developed for Sn where full CI is utilized for the most important transitions, while intermediate-coupling is used for all other levels. We present opacities generated at temperatures and densities related to lithography applications. Our preliminary results indicate that our models are in good agreement with transmission measurements from laser-produced Sn and Xe plasmas.

Authors

  • Amanda Neukirch

    Los Alamos National Laboratory

  • David Kilcrease

    Los Alamos National Laboratory

  • Peter Hakel

    Los Alamos National Laboratory

  • Christopher Fontes

    Los Alamos National Laboratory

  • Manolo Sherrill

    Los Alamos National Laboratory

  • J. P. Colgan

    LANL, Los Alamos National Laboratory, Los Alamos National Laboratory, Los Alamos, NM