Observation of Feshbach resonances in ultracold <sup>107</sup>Ag collisions

ORAL

Abstract

The alkali-like electronic structure of silver (Ag), combined with its large electron affinity, makes it well suited for forming highly polar molecules with alkali atoms using well-established ultracold bi-alkali assembly techniques [1]. Such molecules are predicted to have electric dipole moments of up to ~10 Debye and beyond, rendering them exceptionally attractive for applications in quantum simulation and precision measurement [1,2]. For example, FrAg is extremely sensitive to new physics beyond the Standard Model [3, 4]. 

Creating such “ultrapolar” molecules requires full quantum control over collisional properties of  Ag atoms. Towards achieving this control, we have implemented a dark SPOT MOT to trap ~109 Ag atoms, of both isotopes: 109Ag [5] and 107Ag. We also have implemented  Λ-enhanced gray molasses cooling on the D1 line in both isotopes, achieving temperatures of ~15 μK. These temperatures enable optical dipole trapping of ~106 Ag atoms of either isotope. With these atoms, we report the first observation of Feshbach resonances in 107Ag. We discuss the implications for achieving full control over ultracold Ag-Ag collisions, and progress towards the realization of a BEC of Ag atoms.

[1] J. Kłos et al., New J. Phys. 24, 025005 (2022).

[2] M. Śmiałkowski and M. Tomza, Phys. Rev. A 103, 022802 (2021). 

[3] A. Marc and T. Fleig, Eur. Phys. J. D 78(3), 19 (2025).

[4] V. Spevak et al., Phys. Rev. C 56, 1357 (1997). 

[5] M. Vayninger et al., Phys. Rev. A 112, 063306 (2025).

*We acknowledge support from NSF and the "Table-top experiments for fundamental physics" program, sponsored by the Gordon and Betty Moore Foundation, Simons Foundation, Alfred P. Sloan Foundation, and John Templeton Foundation.

Publication: Vayninger, M., Xiang, A., Bhanushali, N.D., Chen, X., Verma, M., Yang, S., Kapur, R.T., DeMille, D. and Yan, Z.Z. (2025). Magneto-optical trap of silver and potassium atoms. PRA, 112, 063306

Presenters

  • Mohit Verma

    • University of Chicago

Authors

  • Mohit Verma

    • University of Chicago
  • Shaozhen Yang

    • University of Chicago
  • Addison Okell

    • University of Waterloo
  • Silviu-Marian M Udrescu

    • University of Chicago
  • Jacek Klos

    • University of Maryland College Park
    • Physics/JQI/NIST, University of Maryland, College Park MD and Physics, Temple University, Philadelphia, PA
  • Svetlana Kotochigova

    • Temple University
  • Eite Tiesinga

    • National Institute of Standards and Technology (NIST)
  • Alan O Jamison

    • University of Waterloo
  • David DeMille

    • University of Chicago
    • Johns Hopkins University
    • Johns Hopkins University, Argonne National Laboratory, University of Chicago