High Pressure Behavior of Precompressed CO$_{\mathrm{\mathbf{2~}}}$\textbf{Shocked~to~}$\sim $\textbf{10 Mbar}

ORAL

Abstract

CO$_{\mathrm{2}}$ is present in the atmospheres and interiors of Jovian planets, atmospheres of exoplanets, and within Jovian moons. To study the high-pressure behavior of CO$_{\mathrm{2}}$, we used laser-driven shocks to compress CO$_{\mathrm{2}}$, to $\sim $1 TPa (10 Mbar). The CO$_{\mathrm{2}}$ was precompressed in diamond-anvil cells to $\sim $5 kbar, producing liquid at density ($\sim $1.5 ${\mbox{g}} \mathord{\left/ {\vphantom {{\mbox{g}} {\mbox{cm}^{3}}}} \right. \kern-\nulldelimiterspace} {\mbox{cm}^{3}})$, and then shocked by the OMEGA Laser System. Equation of state, temperature, and optical reflectivity were measured between 150 and 950 GPa. CO$_{\mathrm{2}}$ undergoes an insulator-to-conductor transition above $\sim $200 GPa, which may be result from dissociation to metallic oxygen. These data can add to understanding of thermochemical histories of the giant planets. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944.

Authors

  • L. Crandall

    • Laboratory for Laser Energetics, U. of Rochester
  • J.R. Rygg

    • Laboratory for Laser Energetics, U. of Rochester
  • G.W. Collins

    • Laboratory for Laser Energetics, U. of Rochester
  • T.R. Boehly

    • Laboratory for Laser Energetics, U. of Rochester
  • A. Jenei

    • LLNL
  • D.E. Fratanduono

    • LLNL
  • M.C. Gregor

    • LLNL
  • J.H. Eggert

    • LLNL
  • M. Millot

    • LLNL
  • D. Spaulding

    • UC Davis