Negative Ion Extraction from a Pulsed NF3 Plasma

ORAL

Abstract

Negative ions that are ordinarily trapped inside a plasma can be extracted during the afterglow period immediately following the end of a pulse. During this time the ratio of negative ions to electrons dramatically increases because of the electrons higher mobility, enabling them to reach the walls more promptly than the ions. In the later phase of the afterglow an ion ion plasma is formed and negative ions become the dominant negative charge carriers. In this paper we report time resolved measurements of negative ion energy distributions during the on and off period of a pulsed radio frequency inductively coupled discharge at pressures from 20 to 150 mTorr of NF3, peak powers of 1-3 kW at pulse repetition frequencies between 1 and 10 kHz and duty cycles of 20 to 70\%. We show a large flux of negative ions immediately following plasma turnoff. We find that RF pulse repetition frequency, duty cycle and power, can be adjusted to produce efficient negative ion formation. These parameters also control the transition from electron-ion to ion ion plasma. We also show a comparison to a Hybrid Plasma Equipment Model of the steady state plasma properties during the on period and comment on the transient effects observed.

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Authors

  • Svetlana Radovanov

    Varian Semiconductor Equipment Associates

  • Jeffrey L. Putney

    IBM Research, Advanced Micro Devices, Applied Materials, Inc., IMEC v.z.w. 75 Kapeldreef B-3001 Leuven, Belgium, Kyoto University, Nagoya University, Dublin City University, Ireland, ARC CAMS, MPIT, JCU, Australia, INP Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald, Germany, TU Clausthal, MPI Heidelberg, MPI Dresden, Curtin University of Technology, Australian National University, Missouri University of Science \& Technology, Ruhr University Bochum, Hungarian Academy for Science, RLS-M, OSRAM GmbH, Munich, Germany, INP Greifswald, Germany, Ruhr-University of Bochum, Germany, Nagoya University, JST, CREST, Osaka University, JST, CREST, Kyushu University, JST, CREST, Kyushu University, National Institute for Material Physics, National Institute for Laser, Plasma and Radiation Physics, Arizona State University, Naval Research Laboratory, McGill University, Laboratoire EM2C, CNRS UPR288, Ecole Centrale Paris, Dow Corning Plasma Solutions, Midleton, Ireland, Centre for Plasma Physics, Queens University Belfast, Northern Ireland, University of Adelaide, Adelaide, Australia, University of Central Florida, Orlando, FL, Missouri S\&T, Rolla, MO, University of Manchester, Manchester, UK, Missouri University of Science and Technology, Rolla, Missouri, USA, ARC Centre for Antimatter-Matter Studies, University of Adelaide, 5005, Australia, NU Eco-Engineering Co., Ltd., Fuji Machine Mfg. Co., Ltd., Meijo University, Katagiri Engineering Co., Ltd., Dept. of Electrical Engineering, University of Texas at Dallas, The University of Texas Southwestern Medical Center at Dallas, NU System Co., Ltd., NU EcoEngineering Co., Ltd., Wakayama University, Department of Electronic Science and Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan, Muroran Institute of Technology, Nippon Steel Corporation, B and W Group Ltd, The University of Texas at Dallas, Ruhr-University Bochum, Lehrstuhl f. Theoretische Elektrotechnik, 44801 Bochum, Germany, Ruhr-University Bochum, Inst. for Plasma and Atomic Physics, 44780 Bochum, Germany, Ruhr University Bochum, TET, Ruhr University Bochum, AEPT, Tokyo Electron America, University of Houston, IEAP, Christian-Albrechts-Universit\"{a}t, Kiel, INP\,Greifswald, Germany, Nagoya Institute of Technology, Institute for Theoretical and Experimental Physics, Federal State Unitary Enterprise and Moscow Institute of Electronic Technology, Federal State Unitary Enterprise, PLASMANT Research Group, Dept. of Chemistry, Univ. of Antwerp, Arbeitsgruppe Reaktive Plasmen, Fakult\"at f\"ur Physik und Astronomie, Ruhr-Universit\"at Bochum, PIIM, CNRS - Universite de Provence, LPTP, Ecole Polytechnique, Laplace, Universite Paul Sabatier, Institute of Plasma Physics AS CR, v.v.i., Hokkaido Univ., NIT, Chiba Institute of Technology, The University of Tokushima, Ruhr-University Bochum, TET, Ruhr-University Bochum, AEPT, IPFN IST Lisboa, LPGP UPS Orsay, Tokyo Electron Ltd., Keio University, Tokyo Institute of Technology, Max-Planck-Institut f\"ur Kernphysik, Institut f\"ur Theoretische Physik, TU Clausthal, Curtin University, Perth, Australia, Max-Planck-Institut fur Kernphysik, Missouri University of Science and Technology, NRL, Berkeley Scholars Inc., Department of Physics, Florida A\&M University, Department of Physics, University of Rajshahi, Rajshahi, Bangladesh, Max-Planck-Institute for Nuclear Physics, Heidelberg, Germany, Nicolaus Copernicus University, Institute of Physics, Grudziadzka 5/7, 87-100 Torun, Poland, CAMS, Australian National University, York University, Canada, University of Wisconsin, Florida Tech, Depoartment of Physics, Florida A\&M University, Lamar University, Institute of Semiconductor Physics, 630090 Novosibirsk, Russia, Max-Planck-Institut f\"ur Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg, Germany, University of Adelaide, Max-Planck Inst. fuer Kernphysik, Heidelberg, Kansas State University (now University of Madrid), Lawrence Berkeley National Laboratory and University of California, Davis, Lawrence Berkeley National Laboratory, Max-Planck Institut fuer Kernphysik, Heidelberg, Kansas State University, University of Madrid, National Institute for Laser, Plasma and Radiation Physics, Romania, INP Greifswald, Felix-Hausdorff-Str. 2, D-17489 Greifswald, Germany, Department of Electrical and Computer Engineering, Colorado State University, Fort Collins, Colorado 80523, Department of Mechanical Engineering, Colorado State University, Fort Collins, Colorado 80523, Hanyang University, University of Wisconsin-Madison, WVU, ISSI, Inc., UES, Inc., University of Texas at Dallas, Verity Instruments, University of Illinois at Urbana-Champaign, LPTP, CNRS, France, University of Wyoming, Institute of Solid State Physics of Bulgarian Academy of Sciences, Sofia, Bulgaria, Institute of Physics, Belgrade, Serbia, ISSI Inc., West Virginia University, St. Petersburg State University, Nagasaki University, Link\"oping University, Department of Electrical and Computer Engineering, Colorado State University, Fort Collins, Colorado 80523., Tokyo Tech., Nagoya UNiversity, Air Force Research Laboratory, Wright-Patterson AFB, OH 45433, Innovative Scientific Solutions, Inc., Dayton, OH 45440, Electrical Engineering, Hanyang University, Republic of Korea, Department of Physics, Wesleyan University, Middletown, USA, Universidade Estadual de Campinas- Unicamp, Campinas, Brazil, DMS Co., Ltd., Suwon, 445-810, Korea, Department of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746, Korea, Varian Semiconductor Equipment Associates, Department of Chemistry and Division Energy Systems Research, Ajou University, Suwon 443-749, Korea, Nagoya Univ. and JST-CREST, Kyushu Univ. and JST-CREST, Osaka Univ. and JST-CREST, Nagoya Urban Industries Promotion Corp., Universidad de Antioquia, Columbia, Loras College, Universidad Autonoma de Madrid, LBL, University of Newcastle, University of Nebraska, Lawrence Berkeley National Lab and University of California, Davis, Lawrence Berkeley National Lab, Universidad Autonoma de Madrid, Spain, University of California, Davis, LPTP, Palaiseau, France, LSP, Grenoble, France, Queen's University Belfast, Ruhr-Universitaet Bochum, Laboratory for Optical Physics and Engineering, University of Illinois at Urbana-Champaign

  • Jeffrey L. Putney

    IBM Research, Advanced Micro Devices, Applied Materials, Inc., IMEC v.z.w. 75 Kapeldreef B-3001 Leuven, Belgium, Kyoto University, Nagoya University, Dublin City University, Ireland, ARC CAMS, MPIT, JCU, Australia, INP Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald, Germany, TU Clausthal, MPI Heidelberg, MPI Dresden, Curtin University of Technology, Australian National University, Missouri University of Science \& Technology, Ruhr University Bochum, Hungarian Academy for Science, RLS-M, OSRAM GmbH, Munich, Germany, INP Greifswald, Germany, Ruhr-University of Bochum, Germany, Nagoya University, JST, CREST, Osaka University, JST, CREST, Kyushu University, JST, CREST, Kyushu University, National Institute for Material Physics, National Institute for Laser, Plasma and Radiation Physics, Arizona State University, Naval Research Laboratory, McGill University, Laboratoire EM2C, CNRS UPR288, Ecole Centrale Paris, Dow Corning Plasma Solutions, Midleton, Ireland, Centre for Plasma Physics, Queens University Belfast, Northern Ireland, University of Adelaide, Adelaide, Australia, University of Central Florida, Orlando, FL, Missouri S\&T, Rolla, MO, University of Manchester, Manchester, UK, Missouri University of Science and Technology, Rolla, Missouri, USA, ARC Centre for Antimatter-Matter Studies, University of Adelaide, 5005, Australia, NU Eco-Engineering Co., Ltd., Fuji Machine Mfg. Co., Ltd., Meijo University, Katagiri Engineering Co., Ltd., Dept. of Electrical Engineering, University of Texas at Dallas, The University of Texas Southwestern Medical Center at Dallas, NU System Co., Ltd., NU EcoEngineering Co., Ltd., Wakayama University, Department of Electronic Science and Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan, Muroran Institute of Technology, Nippon Steel Corporation, B and W Group Ltd, The University of Texas at Dallas, Ruhr-University Bochum, Lehrstuhl f. Theoretische Elektrotechnik, 44801 Bochum, Germany, Ruhr-University Bochum, Inst. for Plasma and Atomic Physics, 44780 Bochum, Germany, Ruhr University Bochum, TET, Ruhr University Bochum, AEPT, Tokyo Electron America, University of Houston, IEAP, Christian-Albrechts-Universit\"{a}t, Kiel, INP\,Greifswald, Germany, Nagoya Institute of Technology, Institute for Theoretical and Experimental Physics, Federal State Unitary Enterprise and Moscow Institute of Electronic Technology, Federal State Unitary Enterprise, PLASMANT Research Group, Dept. of Chemistry, Univ. of Antwerp, Arbeitsgruppe Reaktive Plasmen, Fakult\"at f\"ur Physik und Astronomie, Ruhr-Universit\"at Bochum, PIIM, CNRS - Universite de Provence, LPTP, Ecole Polytechnique, Laplace, Universite Paul Sabatier, Institute of Plasma Physics AS CR, v.v.i., Hokkaido Univ., NIT, Chiba Institute of Technology, The University of Tokushima, Ruhr-University Bochum, TET, Ruhr-University Bochum, AEPT, IPFN IST Lisboa, LPGP UPS Orsay, Tokyo Electron Ltd., Keio University, Tokyo Institute of Technology, Max-Planck-Institut f\"ur Kernphysik, Institut f\"ur Theoretische Physik, TU Clausthal, Curtin University, Perth, Australia, Max-Planck-Institut fur Kernphysik, Missouri University of Science and Technology, NRL, Berkeley Scholars Inc., Department of Physics, Florida A\&M University, Department of Physics, University of Rajshahi, Rajshahi, Bangladesh, Max-Planck-Institute for Nuclear Physics, Heidelberg, Germany, Nicolaus Copernicus University, Institute of Physics, Grudziadzka 5/7, 87-100 Torun, Poland, CAMS, Australian National University, York University, Canada, University of Wisconsin, Florida Tech, Depoartment of Physics, Florida A\&M University, Lamar University, Institute of Semiconductor Physics, 630090 Novosibirsk, Russia, Max-Planck-Institut f\"ur Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg, Germany, University of Adelaide, Max-Planck Inst. fuer Kernphysik, Heidelberg, Kansas State University (now University of Madrid), Lawrence Berkeley National Laboratory and University of California, Davis, Lawrence Berkeley National Laboratory, Max-Planck Institut fuer Kernphysik, Heidelberg, Kansas State University, University of Madrid, National Institute for Laser, Plasma and Radiation Physics, Romania, INP Greifswald, Felix-Hausdorff-Str. 2, D-17489 Greifswald, Germany, Department of Electrical and Computer Engineering, Colorado State University, Fort Collins, Colorado 80523, Department of Mechanical Engineering, Colorado State University, Fort Collins, Colorado 80523, Hanyang University, University of Wisconsin-Madison, WVU, ISSI, Inc., UES, Inc., University of Texas at Dallas, Verity Instruments, University of Illinois at Urbana-Champaign, LPTP, CNRS, France, University of Wyoming, Institute of Solid State Physics of Bulgarian Academy of Sciences, Sofia, Bulgaria, Institute of Physics, Belgrade, Serbia, ISSI Inc., West Virginia University, St. Petersburg State University, Nagasaki University, Link\"oping University, Department of Electrical and Computer Engineering, Colorado State University, Fort Collins, Colorado 80523., Tokyo Tech., Nagoya UNiversity, Air Force Research Laboratory, Wright-Patterson AFB, OH 45433, Innovative Scientific Solutions, Inc., Dayton, OH 45440, Electrical Engineering, Hanyang University, Republic of Korea, Department of Physics, Wesleyan University, Middletown, USA, Universidade Estadual de Campinas- Unicamp, Campinas, Brazil, DMS Co., Ltd., Suwon, 445-810, Korea, Department of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746, Korea, Varian Semiconductor Equipment Associates, Department of Chemistry and Division Energy Systems Research, Ajou University, Suwon 443-749, Korea, Nagoya Univ. and JST-CREST, Kyushu Univ. and JST-CREST, Osaka Univ. and JST-CREST, Nagoya Urban Industries Promotion Corp., Universidad de Antioquia, Columbia, Loras College, Universidad Autonoma de Madrid, LBL, University of Newcastle, University of Nebraska, Lawrence Berkeley National Lab and University of California, Davis, Lawrence Berkeley National Lab, Universidad Autonoma de Madrid, Spain, University of California, Davis, LPTP, Palaiseau, France, LSP, Grenoble, France, Queen's University Belfast, Ruhr-Universitaet Bochum, Laboratory for Optical Physics and Engineering, University of Illinois at Urbana-Champaign

  • Jeffrey L. Putney

    IBM Research, Advanced Micro Devices, Applied Materials, Inc., IMEC v.z.w. 75 Kapeldreef B-3001 Leuven, Belgium, Kyoto University, Nagoya University, Dublin City University, Ireland, ARC CAMS, MPIT, JCU, Australia, INP Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald, Germany, TU Clausthal, MPI Heidelberg, MPI Dresden, Curtin University of Technology, Australian National University, Missouri University of Science \& Technology, Ruhr University Bochum, Hungarian Academy for Science, RLS-M, OSRAM GmbH, Munich, Germany, INP Greifswald, Germany, Ruhr-University of Bochum, Germany, Nagoya University, JST, CREST, Osaka University, JST, CREST, Kyushu University, JST, CREST, Kyushu University, National Institute for Material Physics, National Institute for Laser, Plasma and Radiation Physics, Arizona State University, Naval Research Laboratory, McGill University, Laboratoire EM2C, CNRS UPR288, Ecole Centrale Paris, Dow Corning Plasma Solutions, Midleton, Ireland, Centre for Plasma Physics, Queens University Belfast, Northern Ireland, University of Adelaide, Adelaide, Australia, University of Central Florida, Orlando, FL, Missouri S\&T, Rolla, MO, University of Manchester, Manchester, UK, Missouri University of Science and Technology, Rolla, Missouri, USA, ARC Centre for Antimatter-Matter Studies, University of Adelaide, 5005, Australia, NU Eco-Engineering Co., Ltd., Fuji Machine Mfg. Co., Ltd., Meijo University, Katagiri Engineering Co., Ltd., Dept. of Electrical Engineering, University of Texas at Dallas, The University of Texas Southwestern Medical Center at Dallas, NU System Co., Ltd., NU EcoEngineering Co., Ltd., Wakayama University, Department of Electronic Science and Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan, Muroran Institute of Technology, Nippon Steel Corporation, B and W Group Ltd, The University of Texas at Dallas, Ruhr-University Bochum, Lehrstuhl f. Theoretische Elektrotechnik, 44801 Bochum, Germany, Ruhr-University Bochum, Inst. for Plasma and Atomic Physics, 44780 Bochum, Germany, Ruhr University Bochum, TET, Ruhr University Bochum, AEPT, Tokyo Electron America, University of Houston, IEAP, Christian-Albrechts-Universit\"{a}t, Kiel, INP\,Greifswald, Germany, Nagoya Institute of Technology, Institute for Theoretical and Experimental Physics, Federal State Unitary Enterprise and Moscow Institute of Electronic Technology, Federal State Unitary Enterprise, PLASMANT Research Group, Dept. of Chemistry, Univ. of Antwerp, Arbeitsgruppe Reaktive Plasmen, Fakult\"at f\"ur Physik und Astronomie, Ruhr-Universit\"at Bochum, PIIM, CNRS - Universite de Provence, LPTP, Ecole Polytechnique, Laplace, Universite Paul Sabatier, Institute of Plasma Physics AS CR, v.v.i., Hokkaido Univ., NIT, Chiba Institute of Technology, The University of Tokushima, Ruhr-University Bochum, TET, Ruhr-University Bochum, AEPT, IPFN IST Lisboa, LPGP UPS Orsay, Tokyo Electron Ltd., Keio University, Tokyo Institute of Technology, Max-Planck-Institut f\"ur Kernphysik, Institut f\"ur Theoretische Physik, TU Clausthal, Curtin University, Perth, Australia, Max-Planck-Institut fur Kernphysik, Missouri University of Science and Technology, NRL, Berkeley Scholars Inc., Department of Physics, Florida A\&M University, Department of Physics, University of Rajshahi, Rajshahi, Bangladesh, Max-Planck-Institute for Nuclear Physics, Heidelberg, Germany, Nicolaus Copernicus University, Institute of Physics, Grudziadzka 5/7, 87-100 Torun, Poland, CAMS, Australian National University, York University, Canada, University of Wisconsin, Florida Tech, Depoartment of Physics, Florida A\&M University, Lamar University, Institute of Semiconductor Physics, 630090 Novosibirsk, Russia, Max-Planck-Institut f\"ur Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg, Germany, University of Adelaide, Max-Planck Inst. fuer Kernphysik, Heidelberg, Kansas State University (now University of Madrid), Lawrence Berkeley National Laboratory and University of California, Davis, Lawrence Berkeley National Laboratory, Max-Planck Institut fuer Kernphysik, Heidelberg, Kansas State University, University of Madrid, National Institute for Laser, Plasma and Radiation Physics, Romania, INP Greifswald, Felix-Hausdorff-Str. 2, D-17489 Greifswald, Germany, Department of Electrical and Computer Engineering, Colorado State University, Fort Collins, Colorado 80523, Department of Mechanical Engineering, Colorado State University, Fort Collins, Colorado 80523, Hanyang University, University of Wisconsin-Madison, WVU, ISSI, Inc., UES, Inc., University of Texas at Dallas, Verity Instruments, University of Illinois at Urbana-Champaign, LPTP, CNRS, France, University of Wyoming, Institute of Solid State Physics of Bulgarian Academy of Sciences, Sofia, Bulgaria, Institute of Physics, Belgrade, Serbia, ISSI Inc., West Virginia University, St. Petersburg State University, Nagasaki University, Link\"oping University, Department of Electrical and Computer Engineering, Colorado State University, Fort Collins, Colorado 80523., Tokyo Tech., Nagoya UNiversity, Air Force Research Laboratory, Wright-Patterson AFB, OH 45433, Innovative Scientific Solutions, Inc., Dayton, OH 45440, Electrical Engineering, Hanyang University, Republic of Korea, Department of Physics, Wesleyan University, Middletown, USA, Universidade Estadual de Campinas- Unicamp, Campinas, Brazil, DMS Co., Ltd., Suwon, 445-810, Korea, Department of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746, Korea, Varian Semiconductor Equipment Associates, Department of Chemistry and Division Energy Systems Research, Ajou University, Suwon 443-749, Korea, Nagoya Univ. and JST-CREST, Kyushu Univ. and JST-CREST, Osaka Univ. and JST-CREST, Nagoya Urban Industries Promotion Corp., Universidad de Antioquia, Columbia, Loras College, Universidad Autonoma de Madrid, LBL, University of Newcastle, University of Nebraska, Lawrence Berkeley National Lab and University of California, Davis, Lawrence Berkeley National Lab, Universidad Autonoma de Madrid, Spain, University of California, Davis, LPTP, Palaiseau, France, LSP, Grenoble, France, Queen's University Belfast, Ruhr-Universitaet Bochum, Laboratory for Optical Physics and Engineering, University of Illinois at Urbana-Champaign