Vibrationally-resolved electron-impact excitation of molecular hydrogen

ORAL

Abstract

Molecular hydrogen and its isotopologues are present in a range of vibrationally excited states in fusion, atmospheric, and interstellar plasmas. Electron-impact excitation cross sections resolved in both final and initial vibrational levels of the target are required for modeling the properties of many low-temperature plasmas. Measurements of excitations in H$_2$ are typically limited to scattering on the ground vibrational state, and hence there is significant demand for accurate theoretical calculations of scattering on excited states. At low to intermediate energies, the currently recommended data are up to a factor of two higher than the available measurements for scattering on the ground vibrational state. Recent calculations performed using the convergent close-coupling (CCC) method have demonstrated the convergence of excitation cross sections with respect to the number of coupled channels, and yielded good agreement with experiment for scattering on the ground vibrational level of H$_2$. Here we extend the CCC method to provide a fully vibrationally-resolved description of e-H$_2$ scattering, providing results for excitation of all vibrational levels in several low lying singlet and triplet states, from all vibrational levels of the ground state.

Authors

  • Liam Scarlett

    Curtin University

  • Jonathan Tapley

    Curtin University

  • Dmitry Fursa

    Curtin University

  • Jeremy Savage

    Curtin University

  • Igor Bray

    Curtin University

  • Mark Zammit

    Los Alamos National Laboratory