Comments on Electrostatic Persistence Length
ORAL
Abstract
I have shown that the quadratic dependence of the electrostatic persistence length on the Debye screening length obtained in the classical Odijk-Skolnick-Fixman (OSF) theory is a result of incorrect assumption made about the energetic penalty for chain deformation. By including chain elasticity the linear dependence of the electrostatic persistence length on the Debye screening length is obtained. This result is derived by applying simple scaling analysis of the angle fluctuations and Gaussian variational principle to the system of strongly and weakly charged polymer chains.
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Authors
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Andrey Dobrynin
Institute of Materials Science and Department of Physics, University of Connecticut, Institute of Materials Science, University of Connecticut, Storrs, CT 06269-3136