Fluctuation dynamics of water-hydrophobic interface

ORAL

Abstract

Previous x-ray reflectivity measurements of the interface between water and hydrophobic surfaces with contact angle $>$100\r{ } indicate the existence of depletion layer. However, x-ray measurements provide little information of the fluctuation dynamics. In this presentation, surface plasmon resonance imaging technique with $<$ 1ms temporal resolution and $<$ 1$\mu $m lateral resolution has been built to investigate interface between water and methyl-terminated gold surface. This technique enables to examine the fluctuation dynamics of the depletion layer with temporal and spatial correlation analysis. The characteristic time and length scales of this fluctuation are explored.

Authors

  • Sung Chul Bae

    University of Illinois at Urbana-Champaign, University of Illinois

  • Adele Poynor

    Allegheny College, University of Illinois

  • Steve Granick

    Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, University of Illinois at Urbana-Champaign, University of Illinois, Dept of Materials Science and Engineering, Univ of Illinois at Urbana-Champaign, Dept. of Material Science and Engineering, University of Illinois at Urbana and Champaign