Enhanced thermoelectric properties in silicon nanowires

ORAL

Abstract

Recently, we demonstrated that silicon nanowires can be designed and fabricated to achieve an approximately 100-fold enhancement in thermoelectric efficiency compared to bulk silicon. Independent measurements of thermoelectric power, and thermal and electrical conductivities suggest that this improvement is due to phonon effects rather than quantum confinement. Here, we present the study of the scaling laws (i.e. nanowire length/width dependence) for the phonon dynamics and transport. We investigate the influence of the phonon drag, carrier mobility and doping on the thermoelectric properties, and the universality of these findings. This work is supported by the Office of Naval Research, the Department of Energy, the National Science Foundation, and the Defense Advanced Research Projects Agency.

Authors

  • Slobodan Mitrovic

    Division of Chemistry and Chemical Engineering, Caltech, Pasadena, CA 91125

  • Jen-Kan Yu

    Division of Chemistry and Chemical Engineering, Caltech, Pasadena, CA 91125

  • Akram Boukai

    Division of Chemistry and Chemical Engineering, Caltech, Pasadena, CA 91125

  • Jamil Tahir-Kheli

    Division of Chemistry and Chemical Engineering, Caltech, Pasadena, CA 91125

  • William A. Goddard

    California Institute of Technology, Division of Chemistry and Chemical Engineering, Caltech, Pasadena, CA 91125

  • James R. Heath

    Division of Chemistry and Chemical Engineering, Caltech, Pasadena, CA 91125