Oxygen Sublattice Tuning of Magnetic Order in the Kagom\'{e} Antiferromagnet YBaCo$_{4}$O$_{7+\delta}$

ORAL

Abstract

YBaCo$_{4}$O$_{7+\delta}$ (Y-114) is a relatively new compound that contains the Kagom\'{e} net motif and is structurally related to the pyrochlore lattice, differing only in the stacking of the triangular layers that link successive Kagom\'{e} planes. We have previously shown that the stoichiometric compound orders antiferromagnetically (AFM) at T$_{N}$ = 108 K into a structure that compromises a collinear arrangement along the $c$-axis and a 120$^{o}$ structure (akin to the well-known $\sqrt{3} \mbox{x} \sqrt{3}$ supercell) in the Kagom\'{e} planes. This ordered state is considered to result from a symmetry-breaking structural distortion that lifts the geometric frustration. Here we show from neutron diffraction the effect of added oxygen on the structure and magnetism of the parent compound. By controlling this parameter, we can tune the system from the AFM ordered ground state into a disordered state. We discuss two possible mechanisms for this evolution: (1) suppressed structural distortion leading to geometric frustration, and (2) the formation of S=0 Co$^{3+}$ centers that can break magnetic exchange pathways.

Authors

  • John Mitchell

    Materials Science Division, Argonne National Laboratory, 9700 S. Cass Ave, Argonne IL 60439, Mat. Sci. Div., ANL, Argonne National Laboratory, Materials Science Division, Argonne National Laboratory, LANL, Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA, Argonne Natl Lab, Materials Science Division, Argonne National Laboratory, Argonne, IL, Argonne National Lab

  • O. Chmaissem

    Department of Physics, Northern Illinois University, DeKalb, IL 60115, Materials Science Division, Argonne National Laboratory, Argonne, IL 60439

  • H. Zheng

    Argonne National Laboratory, Materials Science Division, Argonne National Laboratory, 9700 S. Cass Ave, Argonne IL 60439

  • A. Huq

    Oak Ridge National Laboratory

  • P. Stephens

    SUNY Stony Brook