Thermal conductivity of isolated and interacting carbon nanotubes

ORAL

Abstract

We have investigated the thermal conductivity of single wall carbon nanotubes (SWCNT) either isolated or in contact with external media, by using equilibrium molecular dynamics and the Boltzmann transport equation\footnote{Chantrenne {\sl et al.} J. Appl. Phys. \textbf{97}, 104318 (2005).}. We show that, contrary to existing controversies, both methods yield a finite value of the thermal conductivity for infinitely long tubes, as opposed to the case of 1D momentum conserving systems\footnote{O. Narayan and S. Ramaswamy, Phys. Rev. Lett. \textbf{89}, 200601 (2002).}. Acoustic and flexure modes with mean free paths of the order of a few micron, as observed also in experiments\footnote{C.~Yu, {\sl et al.} Nano Lett. \textbf{5}, 1842 (2005).}, are identified as major contributors to the high value of SWCNT conductivity. We also find that the interaction with an external medium may substantially decrease the lifetime of the low frequency vibrations, reducing the thermal conductivity by up to two orders of magnitude.

Authors

  • Davide Donadio

    UC Davis, ETH Zurich, Department of Chemistry, University of California, Davis

  • Giulia Galli

    University of California-Davis, UC Davis, Department of Chemistry, University of California, Davis, University of California, Davis, Department of Chemistry, University of California, Davis, CA 95616, USA, University of California Davis