Structure and dynamics of a coarsening emulsion

ORAL

Abstract

We investigate the structure and dynamics of a non-aqueous coarsening emulsion. The experiment is performed on an index and density matched emulsion prepared by homogenization with droplets occupying approximately 80\% of the volume fraction. Three dimensional visualizations of the droplets are obtained by fluorescent confocal microscopy at different time intervals as the emulsion coarsens. We find that the droplet size distribution matches a Weibull distribution. The pair coordination function as a function of droplet core size shows a peculiar liquid structure where small droplets fill the interstices between big ones. While we observe self similar behavior in droplet growth, the evolution of the droplet size distribution departs from that predicted by mean field theory.

Authors

  • Klebert Feitosa

    Dept. of Chemical and Biomolecular Engineering, University of Pennsylvania

  • John Crocker

    Dept. of Chemical and Biomolecular Engineering. University of Pennsylvania, Department of Chemical and Biomolecular Engineering, University of Pennsylvania, Philadelphia, PA, University of Pennsylvania