Persistence length of a linear polyelectrolyte in the presence of salt

ORAL

Abstract

The conformational behavior of polyelectrolytes is important in various contexts, including the self-assembly behavior of biopolymers and their properties under confinement. A key parameter is the persistence length, which quantifies the rigidity of the polyelectrolyte. Despite much study, a debate exists about the dependence of the electrostatic persistence length on the Debye screening length. Since most theories and simulation studies treat the electrostatic interaction via the Debye--H\"{u}ckel potential, a mean-field approximation, these may not fully resolve the role of salt concentration. In this study, we simulate a polyelectrolyte with \emph{explicit} counterions and salt. The response of the persistence length to variation in ionic strength is compared to the Odijk--Skolnick--Fixman theory.

Authors

  • Wei Qu

    Northwestern University

  • Erik Luijten

    Northwestern University