Theory of volume phase transitions of polyelectrolyte gels

ORAL

Abstract

We will present theoretical results for the effect of charge regularization accompanying volume phase transitions of polyelectrolyte gels. Our theoretical formulation of the cascade effect that couples the effective degree of ionization and the polymer density leads to significant deviations from the classical Flory-type theories.

Authors

  • Jing Hua

    University of Massachusetts, Amherst

  • Mithun Mitra

    University of Massachusetts, Amherst

  • Murugappan Muthukumar

    University of Massachusetts, Amherst, University of Massachusetts