Stronger phonon scattering by larger differences in atomic mass and size in p-type half-Heuslers Hf$_{1-x}$Ti$_{x}$CoSb$_{0.8}$Sn$_{0.2}$

ORAL

Abstract

High lattice thermal conductivity has been the bottleneck for further improvement of thermoelectric figure-of-merit (ZT) of half-Heuslers (HHs) Hf$_{1-x}$Zr$_{x}$CoSb$_{0.8}$Sn$_{0.2}$. Theoretically the high lattice thermal conductivity can be reduced by exploring larger differences in atomic mass and size in the crystal structure. In this paper, we experimentally demonstrated that lower than ever reported thermal conductivity in p-type HHs can indeed be achieved when Ti is used to replace Zr, i.e., Hf$_{1-x}$Ti$_{x}$CoSb$_{0.8}$Sn$_{0.2}$, due to larger differences in atomic mass and size between Hf and Ti than Hf and Zr. The highest peak ZT of about 1.1 in the system Hf$_{1-x}$Ti$_{x}$CoSb$_{0.8}$Sn$_{0.2}$ (x=0.1, 0.2, 0.3, and 0.5) was achieved with x=0.2 at 800 $^{o}$C.

Authors

  • Xiao Yan

    Boston College

  • Weishu Liu

    Boston College

  • Hui Wang

    Boston College

  • Shuo Chen

    Boston College

  • Junichiro Shiomi

    The University of Tokyo

  • Hengzhi Wang

    Boston College

  • Dezhi Wang

    Boston College

  • Gang Chen

    Massachusetts Institute of Technology, MIT

  • Zhifeng Ren

    Boston College