Charge transfer and magnetism in (LaNiO$_3$)$_n$/(LaMnO$_3$)$_2$ superlattices

ORAL

Abstract

Interfaces in solids have been an enduring them in materials physics, where dimensionality and proximity effects cooperate to create interfacial states that are distinct from their bulk counterparts. In this work, we investigate the interfacial ferromagnetism induced in the the paramagnetic metal LaNiO$_3$ via proximity to the antiferrmagnetic insulator LaMnO$_3$. We fabricated a series of (LaNiO$_3$)$_n$/(LaMnO$_3$)$_2$ ($2 \leq n \leq 5$) digital superlattices on (001) SrTiO$_3$ substrates using ozone-assisted molecular beam epitaxy. The total superlattice thickness is maintained at $\sim$30 nm by varying the number of superlattice periods. X-ray absorption and x-ray magnetic circular dichroism measurements at the Mn and Ni $L$-edges confirm the presence of charge-transfer at the LaNiO$_3$/LaMnO$_3$ interface, with magnetism residing on both Mn and Ni sites. Magnetotransport measurements performed on superlattices with $n \leq 3$ show insulating behavior between 5 K and 300 K, while samples with $n$ = 4,5 are metallic. We observe an anomalous Hall effect in the sample with $n = 4$, that vanishes in the more metallic $n = 5$ sample. We discuss possible models for the electronic and magnetic behavior of LaNiO$_3$.

Authors

  • Jason Hoffman

    Argonne National Laboratory, Materials Science Division, Argonne National Lab

  • I-Cheng Tung

    Northwestern University

  • Brittany Nelson-Cheeseman

    School of Engineering, University of St. Thomas \& Materials Science Division, Argonne National Laboratory, Argonne National Laboratory

  • Ming Liu

    Argonne National Laboratory

  • John Freeland

    Argonne National Laboratory

  • Anand Bhattacharya

    Argonne National Laboratory, Materials Science Division \& Center for Nanoscale Materials, Argonne National Lab, Argonne National Lab, Materials Science Division and Center for Nanoscale Materials, Argonne National Laboratory