Packing of charged chains on toroidal geometries?

ORAL

Abstract

We study sequential Langmuir adsorption of a flexible charged polyelectrolyte chain on tori. In the regime of monomer-monomer electrostatic interaction dominating over thermal fluctuations, it becomes a generalized Thomson problem. Various patterns of adsorbed chain are found including double spirals, disclination-like structures, Janus tori and uniform wrappings, arising from the long-range electrostatic interaction and the toroidal geometry. Their broken mirror symmetry and energetics are analyzed. In particular, we find a power law for the electrostatic energy; the dependence of the power on the geometry of tori implies a geometric origin. Furthermore, in the regime of large thermal fluctuation, we systematically study random walks on tori that generate chain configurations; the features associated with the toroidal geometry are discussed.

Authors

  • Zhenwei Yao

    Northwestern University

  • Monica Olvera de la Cruz

    Northwestern University, Department of Materials Science, Northwestern University, Evanston, IL 60208, USA, Department of Materials Science and Engineering, Northwestern University, Materials Science and Engineering, Northwestern University