Evolution of dynamical facilitation approaching the glass transition

ORAL

Abstract

We investigate the relaxation dynamics of simulated dense bidimensional supercooled liquids composed of softly interacting particles. We show that the long time scale dynamical heterogeneities result from the aggregation of several elementary relaxation events, themselves formed by collective leaps. By varying the temperature, we show that for low temperatures there is a growing excess of probability to find cage jumps that are close both in space and time, and that the network of spatio-temporal facilitation evolves towards a collection of clearly defined large events. We discuss these observations and specifically the relative importance of facilitation when approaching the glass transition.

Authors

  • Raphael Candelier

    LJP - UPMC

  • Asaph Widmer-Cooper

    School of Chemistry, University of Sydney

  • David Reichman

    Columbia University, Department of Chemistry, Columbia University

  • Giulio Biroli

    IPhT - CEA

  • Olivier Dauchot

    ESPCI, UMR Gulliver CNRS, Paris, France, EC2M - ESPCI, ESPCI ParisTech, ESPCI, Paris, France