Quasi-one-dimensional phonon anomaly in the narrow-gap semiconductor FeSb$_2$

ORAL

Abstract

FeSb$_2$ has a variety of unusual properties, ranging from the temperature-induced electronic paramagnetism to one-dimensional (1D) metallic conductivity at temperatures below $\sim 300$ K and down to $\sim 30$ K, where it becomes insulating, and to giant thermoelectric power factor. While it is generally acknowledged that these properties result from the tight balance between strong covalent hybridization, electronic correlation and the tendency to band delocalization, what exactly are the mechanisms leading to these unusual behaviors remain unclear. In particular, it is a matter of current debate, whether the giant thermoelectric figure of merit observed in FeSb$_2$ is explained by purely correlated-electronic mechanism, or it results from peculiar interaction of electrons with the lattice vibrations - such as the phonon drag effect. Here we present the inelastic neutron scattering survey of the phonon spectra in FeSb$_2$. It reveals phonon dispersions of one-dimensional character, which mirror the 1D metallicity along the $b-$axis, and the quasi-one-dimensional magnetism observed in the insulating sister material CrSb$_2$. Phonon dispersions undergo dramatic changes in the temperature range where electronic paramagnetism emerges, indicating strong coupling to electrons.

Authors

  • Igor Zaliznyak

    Condensed Matter Physics and Material Science Department, Brookhaven National Laboratory, Brookhaven Natl Lab

  • Cedomir Petrovic

    Brookhaven National Laboratory, Brookhaven Natl Lab

  • Rongwei Hu

    Brookhaven National Laboratory, Brookhaven Natl Lab

  • Andrei Savici

    Oak Ridge National Laboratory, Oak Ridge Natl Lab

  • Ovidiu Garlea

    Oak Ridge Natl Lab

  • Barry Winn

    Oak RIdge Natl Lab, Oak Ridge Natl Lab