Equilibrium-like phase transition of a dynamic system

ORAL

Abstract

Dynamic systems are considered to be intrinsically different from systems in thermal equilibrium. Despite this fundamental dichotomy, here we demonstrate that a non-equilibrium, fully dynamical system can display behavior that constitutes a complete analogy to thermal equilibrium phase behavior. This dynamical system, consisting of Janus colloids strongly controlled by external fields and over-damped by a viscous solvent, phase separates like a binary fluid mixture, with a coexistence curve separating mixed and demixed regimes and a critical point that we demonstrate to belong to the 2D Ising universality class. Within the coexistence curve, we locate the spinodal curve that separates spinodal decomposition from nucleation and growth.

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Authors

  • Ming Han

    • Northwestern University
  • Jing Yan

    • University of Illinois at Urbana-Champaign
  • Steve Granick

    • Univ of Illinois - Urbana
    • University of Illinois at Champaign-Urbana
    • University of Illinois, Urbana-Champaign
    • University of Illinois Urbana-Champaign
    • University of Illinois at Urbana-Champaign
    • Departments of Materials Science and Engineering, Chemistry, Physics, University of Illinois
  • Erik Luijten

    • Northwestern University