Magnetic, Transport Properties, Lower Critical Field, Penetration Depth, Anisotropy and Gap Evidences of Ca$_{10}$ (Pt$_{n}$as$_{8})$ (Fe$_{2-X}$Pt$_{x}$As$_{2})_{5}$(n $=$ 3 And 4) Superconductors

POSTER

Abstract

Platinum iron arsenides Ca$_{10}$(Fe$_{1-x}$Pt$_{x}$As)$_{10}$(Pt$_{n}$As$_{8})$ ($n~=$ 3 {\&} 4) are first Fe based superconductors with metallic spacer layers. Crystal structure have stacks of Ca (Pt$_{n}$As$_{8})$ Ca (Fe$_{2}$As$_{2})$ consists of superconducting Fe$_{2}$As$_{2}$ layers alternating with Pt$_{n}$As$_{8}$ layers, forming a triclinic \textit{P1}, 1038phase with $n = $ 3 and tetragonal \textit{P4/n}, 1048phase with $n = $ 4. Two different negatively charged layers [(FeAs)$_{10}$]$^{n-}$ and (Pt$_{3+y}$As$_{8})^{m-}$ compete for electrons provided by Ca$^{2+}$-ions. In parent compound Ca$_{10}$(FeAs)$_{10}$(Pt$_{3}$As$_{8})$, no excess charge dopes FeAs-layer, and superconductivity is induced by Pt-substitution. Additional Pt in Pt$_{4}$As$_{8}$ layer shifts charge balance between layers and T$_{c}$ raises to 38 K, but decreases again if additionally Pt is substituted for Fe. Charge doping is supported by T$_{c}$ $\approx $ 30 K in electron-doped La-1038, x $=$ 0:2 (Ca$_{1-x}$La$_{x})_{10}$(Pt$_{3}$As$_{8})$(Fe$_{2}$As$_{2})_{5}$ without significant Pt-substitution. Magnetic properties were explored. Magnetization measurements reveal fish-tail hysteresis loop and relatively high critical current density at low $T$. Lower critical field,$ H_{c1}$~deduced from vortex penetration into single crystals. Ginsburg-Lauder parameters extracted from reversible magnetizations data. Upper critical field determined by resistive transition shows large anisotropy. With La doping, the structural/magnetic phase transitions are suppressed. $T$ dependency of the $H_{c1}$ is compared with BCS-gap models and anisotropy of $H_{c1}$ will be discussed.

Authors

  • Kalyan Sasmal

    Texas Center for Superconductivity \& Physics at Univ of Houston, Texas Center for Superconductivity, Department of Physics, University of Houston

  • Y.Y. Xue

    Texas Center for Superconductivity, Department of Physics, University of Houston, Texas Center for Superconductivity at the University of Houston, Texas Center for Superconductivity and Department of Physics, University of Houston

  • C.W. Chu

    Texas Center for Superconductivity, Department of Physics, University of Houston, Texas Center for Superconductivity and Department of Physics, University of Houston; Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, TCSUH and Department of Physics, University of Houston