Raman characterization of few-layered 1T'-MoTe$_{\mathrm{2}}$

ORAL

Abstract

Transition metal dichalcogenides (TMDs) exhibit a wealth of physical phenomena that have been studied via electronic transport and optical characterization because of their potential device applications in the 2-D limit. In particular, theory has predicted that a certain subset of TMDs, specifically those in the structurally distorted octahedral (1T') phase, are large-gap quantum spin Hall (QSH) insulators. Here we characterize the thickness of one such TMD, 1T'-MoTe$_{\mathrm{2}}$, down to the monolayer limit using Raman spectroscopy and compare our results to atomic force microscopy (AFM) measurements. Our goal is to determine how thinning it down via micromechanical exfoliation changes the intensities and frequencies of its Raman modes, thus enabling one to track layer dependence in a definitive yet minimally invasive manner in much the same way used for graphene and other layered materials.

Authors

  • Irving P. Herman

    Columbia Univ, Columbia University

  • Dennis Wang

    Columbia Univ, Columbia University

  • Ali Dadgar

    Columbia Univ

  • Sang-Wook Cheong

    Rutgers, The State University of New Jersey, Rutgers University, Rutgers Center for Emergent Materials and Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854, USA, RCEM, Rutgers Univ, Rutgers Univ, Department of Physics \& Astronomy, Rutgers University

  • Abhay Pasupathy

    Columbia university, Columbia Universtiy in the City of New York, Columbia Univ, Columbia University