Metallicity beyond Mott-Ioffe-Regel limit in n-doped strontium titanate

ORAL

Abstract

Cooling oxygen-deficient strontium titanate to liquid-helium temperature leads to a decrease in its electrical resistivity by several orders of magnitude. The temperature dependence of resistivity follows a T-cubic behavior before becoming quadratic in the low-temperature limit, as expected in a Fermi liquid. Here, we show that the roughly cubic resistivity above 100K corresponds to a regime where the quasi-particle mean-free-path is shorter than the electron wave-length and the interatomic distance. These criteria define the Mott-Ioffe-Regel limit. Exceeding this limit occurs in strontium titanate well below room temperature, in contrast to other perovskytes. We argue that the T-cubic resistivity cannot be accounted for by electron-phonon scattering à la Bloch-Gruneisen and consider an alternative scheme based on Landauer transmission between individual dopants hosting polarons. We find a scaling relationship between carrier mobility, the electric permittivity and the frequency of transverse optical soft mode in this temperature range. Providing an account of this observation emerges as a challenge to theory.

Presenters

  • Kamran Behnia

    Laboratoire Physique et Etude de Matériaux (UMR 8213 CNRS-ESPCI), Laboratoire de Physique Et d’Etude des Matériaux (UPMC-CNRS), ESPCI Paris, 10 Rue Vauquelin, ESPCI, ESPCI, LPEM CNRS

Authors

  • Kamran Behnia

    Laboratoire Physique et Etude de Matériaux (UMR 8213 CNRS-ESPCI), Laboratoire de Physique Et d’Etude des Matériaux (UPMC-CNRS), ESPCI Paris, 10 Rue Vauquelin, ESPCI, ESPCI, LPEM CNRS

  • Xiao Lin

    Nanyang Technological University, 10 Rue Vauquelin, ESPCI

  • Willem Rischau

    Laboratoire Physique et Etude de Matériaux (UMR 8213 CNRS-ESPCI), 10 Rue Vauquelin, ESPCI, ESPCI, LPEM CNRS

  • Benoit Fauque

    Laboratoire Physique et Etude de Matériaux (UMR 8213 CNRS-ESPCI), 10 Rue Vauquelin, ESPCI, ESPCI, LPEM CNRS