Observable Thermalization

To understand under which conditions thermodynamics emerges from the microscopic dynamics is the ultimate goal of statistical mechanics. Despite the fact that the theory is more than 100 years old, we are still discussing its foundations and its regime of applicability. A point of crucial importance is the definition of the notion of thermal equilibrium, which is given as the state that maximises the von Neumann entropy. Here we argue that it is necessary to propose a new way of describing thermal equilibrium, focused on observables rather than on the full state of the quantum system. We characterise the notion of thermal equilibrium, for a given observable, via the maximisation of its Shannon entropy and highlight the thermal properties that such a principle heralds. Eventually, we bring to light an intimate connection with the Eigenstate Thermalisation Hypothesis.