Dark excitons and dark polaritons in hybrid perovskites.

ORAL

Abstract

Dark optical processes are often elusive and difficult to quantify. In my talk, I will discuss how exciton/exciton scattering within the manifold of dark (i.e., non-optical) states leads to tell-tale signatures in the non-linear optical response of low-dimensional semiconductors and polariton forming microcavity systems. Our theoretical approach is based on a non-equilibrium/non-stationary stochastic model derived from a composite-boson treatment of electron/hole excitations, allowing us to compute their non-linear coherent optical responses. We shall also discuss how correlated noise can affect the decoherence and fidelity of a quantum state. While the talk will focus on 2D lead-halide perovskite semiconductors, I will make contact with recent experiments of the Silva group in which these materials are embedded in a polaritonic microcavity.

* Funding from the National Science Foundation and the Robert A. Welch Foundation.

Publication: 1.) The Optical Signatures of Stochastic Processes in Many-Body Exciton Scattering, H Li, SA Shah, ARS Kandada, C Silva, A Piryatinski, ER Bittner, Annual Review of Physical Chemistry 74, 467-492 (2023)
2.) Stochastic exciton-scattering theory of optical line shapes: Renormalized many-body contributions, H Li, SA Shah, ER Bittner, A Piryatinski, C Silva-Acuña The Journal of Chemical Physics 157 (5) (2022)
3.) Many-Exciton Quantum Dynamics in a Ruddlesden-Popper Tin Iodide
E Rojas Gatjens, H Li, A Vega Flick, D Cortecchia, A Petrozza, ER Bittner, ... arXiv e-prints, arXiv: 2304.02461

Presenters

  • Eric R Bittner

    University of Houston

Authors

  • Eric R Bittner

    University of Houston