Bringing the SWIR to Silicon with Upconversion Devices

POSTER

Abstract

Infrared imaging, encompassing a spectrum of applications from healthcare to autonomous vehicles, has emphasized the need for advancing Near Infrared (NIR) and Short Wave Infrared (SWIR) detection capabilities. The potential to transform NIR and SWIR photons into detectable NIR photons via upconversion, compatible with prevalent silicon-based cameras, poses a formidable challenge to the current InGaAs sensor-dominated market. This dominance is characterized by intricate fabrication methodologies and heightened device costs, constraining the scalability of imaging solutions in this domain. Our research introduces a paradigm shift through the deployment of solid-state triplet-triplet annihilation upconversion via a charge-transfer state sensitization process. We present a pioneering single-step solution-processed deposition of a bulk heterojunction upconversion film employing organic semiconductors. Demonstrations across varied substrates, including glass and flexible mediums, underscore the versatility and potential of this material system for state-of-the-art upconversion applications.

* Defense Advanced Research Projects Agency grant HR00112220010Part of this work was performed at the Stanford Nano Shared Facilities (SNSF), supported by the National Science Foundation under award ECCS-2026822YW acknowledges financial support from the Office of Naval Research (award N00014-19-1-2453). Use of the Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Contract No. DE-AC02-76SF00515.

Publication: This work is submitted to ACS Nano

Presenters

  • Manchen Hu

    Stanford University

Authors

  • Manchen Hu

    Stanford University

  • Emma Belliveau

    Stanford University

  • Yilei Wu

    Stanford University

  • Pournima Narayanan

    Stanford University

  • Demeng Feng

    University of Wisconsin-Madison, Madison

  • Rabeeya Hamid

    University of Wisconsin-Madison, Madison

  • Natalia Murrietta

    Stanford University

  • Ghada Ahmed

    Stanford University

  • Mikhail A Kats

    University of Wisconsin-Madison, Madison

  • Daniel N Congreve

    Stanford University