Detecting and manipulating individual carbon vacancies in diamond with atomic antennas

ORAL

Abstract

A resonantly excited atomic optical dipole simultaneously generates a propagating (far-) and an evanescent (near-) electromagnetic field. The near-field component diverges in the limit of vanishing distance, indicating an optical antenna with potential for giant near-field intensity enhancement. In principle, any atomic optical dipole in a solid can serve as an optical antenna; however, most of them suffer from environment-induced decoherence that largely mitigates field enhancement. Here, we demonstrate that germanium vacancy centers in diamond - optically-coherent atom-like dipoles in a solid - are exemplary antennas. We measure up to million-fold optical intensity enhancement in the near-field of resonantly excited germanium vacancies. We utilize germanium vacancy antennas to detect and control the charge state of nearby carbon vacancies and generate measurable fluorescence from individual vacancies through Forster resonance energy transfer. Comparison with plasmonic nanospheres - a prototypical near-field enhancement medium -- shows that atomic antennas can generate orders-of-magnitude larger field intensity at nanometer lengthscales. Our study reveals the capacity of atomic antennas for efficient optical energy concentration in solids, with broad applications in spectroscopy, sensing, and quantum science.

* We would like to acknowledge the support from University of Chicago Materials Research Science and Engineering Center, the Pritzker Nanofabrication Facility part of the Pritzker School of Molecular Engineering, the diamond CVD growth at Argonne National Lab, and the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Material Sciences, and Engineering Division.

Presenters

  • Zixi Li

    University of Chicago

Authors

  • Zixi Li

    University of Chicago

  • Xinghan Guo

    University of Chicago

  • Yu Jin

    University of Chicago

  • Francesco Andreoli

    ICFO

  • Anil Bilgin

    University of Chicago

  • David D Awschalom

    University of Chicago

  • Nazar Delegan

    Argonne National Laboratory, Argonne, University of Chicago

  • F. Joseph F Heremans

    Argonne National Laboratory, Argonne National Lab, Argonne, University of Chicago

  • Darrick Chang

    ICFO

  • Giulia Galli

    University of Chicago

  • Alexander A High

    University of Chicago