Harvesting energy from freestanding graphene thermal fluctuations

Highly flexible, electrically conductive freestanding graphene membranes hold great promise for vibration energy harvesting applications. In this study, we present numerical results for a graphene ripple treated as a Brownian particle coupled to an energy harvesting circuit. When circuit and particle are at the same temperature, the second law forbids harvesting energy from the thermal motion of the Brownian particle, even if the circuit contains a rectifying diode. However, when the circuit contains a junction followed by two diodes wired in opposition, a special ultraslow convergence to equilibrium may be imposed. Detailed balance is temporarily broken as current flows between the two diodes and charges two storage capacitors. The harvested energy is taken from the surrounding thermal environment, and we show that the system obeys the first and second laws of thermodynamics.