Canted Antiferromagnetism in Quasi-One-Dimensional iron chalcogenide Ba2FeSe3

ORAL

Abstract

Iron-chalcogenides with quasi-one-dimensional structures are the simplest platforms to study the evolution of magnetism, superconductivity, electronic correlations, and more exotic physics like mott behavior, charge density order, etc. In this study, we report the synthesis and physical properties of quasi-one-dimensional (Q-1D) iron chalcogenide Ba2FeSe3 which consists of corner-shared FeSe4 tetrahedral units commonly seen in the iron chalcogenide superconductors. A high-quality polycrystalline sample was achieved by solid-state reaction methods and characterized by powder X-ray diffraction, electrical resistivity, magnetic susceptibility, and neutron powder diffraction (NPD) measurements. Ba2FeSe3 shows semiconducting behavior and orders antiferromagnetically at Neel temperature (TN) ~ 60 K. The moment canting does not induce a net moment in any direction. Detailed results and implications of magnetic structure will be discussed.

* This work at the University of Texas at Dallas is supported by the US Air Force Office of Scientific Research (AFOSR) (FA9550-19-1-0037), National Science Foundation (NSF) (DMREF-1921581 & 2324033) and Office of Naval Research (ONR) (N00014-23-1-2020). The research conducted at ORNL’s High Flux Isotope Reactor was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy.

Presenters

  • Nikhil Uday Dhale

    The University of Texas at Dallas, University of Texas at Dallas

Authors

  • Nikhil Uday Dhale

    The University of Texas at Dallas, University of Texas at Dallas

  • Keith M Taddei

    Oak Ridge National Lab, Argonne National Lab, Oak Ridge National Laboratory

  • Wenhao Liu

    University of Texas at Dallas

  • Clarina R dela Cruz

    Oak Ridge National Laboratory

  • Bing Lv

    The University of Texas at Dallas, TCSUH and Department of Chemistry, University of Houston.