Nanoscale manipulations of the structural and electronic phases in VO$_{\mathrm{2\thinspace }}$.

ORAL

Abstract

Vanadium Dioxide is a strongly correlated transition metal oxide with a metal-insulator transition at 340 K. Here we studied the phase transitions locally induced in VO$_{\mathrm{2}}$ by biased conducting AFM probe. Firstly, a monoclinic to rutile-like structural transition can be produced by positive probe biases in air. This effect is attributed to the field ionization of surface adsorbed water and the subsequent ion injection into the VO$_{\mathrm{2}}$ film. Secondly, a very stable layered structure can be generated from the rutile-like phase. The nature of the new phase, likely VO$_{\mathrm{2}}$. H$_{\mathrm{2}}$O, is still under active investigations. Near field scanning optical microscopy, Raman spectroscopy and electrical measurements were performed to image the phase transitions in nanoscale and characterize the related physical properties changes.

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Authors

  • Mina Aziziha

    West Virginia Univ

  • Dustin Schrecongost

    West Virginia Univ

  • Weitao Dai

    West Virginia Univ

  • Shahab Derakhshan

    Drexel University, Univ of Delaware, Princeton University, Naval Surface Warfare Center\Carderock Division\West Bethesda site, Naval Surface Warfare Center and Georgetown Univ., Dept. of Physics and Astronomy, University of Delaware, Dept. of Physics and Astronomy, University of Deleware, Dept. of Physics and Astronomy, University of Nevada-Reno, university of Delaware, Contributors, Department of Physics, Astronomy and Geosciences, Towson University, Choice Research Group, Univ of the Sciences in Philadephia, Rutgers Univ, National Institute of Standards and Technology, Department of Chemistry, West Chester University, West Chester, PA 19383, Bucknell University, Towson University, University of Maryland, College of William and Mary, Naval Research Laboratory, Department of Physics, Villanova University, Department of Chemistry, Faculty of Medicine, University of Brescia, Department of Chemistry, State University of New York at Potsdam, Delaware State University DE, NIH Bethesda MD, Wilmington Friends School DE, University Of Rochester NY, Delaware State University, Department of Physics and Astronomy,West Virginia University, The National Energy Technology Laboratory, Non-tenure track professor at research institution, Government Sponsored Laboratory, Research and Development at Industrial Company, Tenure-track Professor at 4 yr college, Department of Physics and Astronomy and Department of Chemistry and Biochemistry, University of Delaware, Biology and Soft Matter Division, Oak Ridge National Laboratory, and Department of Physics and Astronomy, The University of Tennessee, Biology and Soft Matter Division, Oak Ridge National Laboratory, Lehigh Univ, Johns Hopkins Univ, NIST, GMU, GWU, Lock Haven University of PA, Univ of Maryland-Balt County; Center for Nanoscale Materials, Argonne National Laboratory, Department of Chemistry, Northwestern University, Univ of Maryland-Balt County, Pennsylvania State University, BAE Systems, Inc., Nashua, New Hampshire 03061, Department of Physics, West Virginia University, Morgantown, West Virginia, 26506-6315, California State University, Long Beach

  • Shahab Derakhshan

    Drexel University, Univ of Delaware, Princeton University, Naval Surface Warfare Center\Carderock Division\West Bethesda site, Naval Surface Warfare Center and Georgetown Univ., Dept. of Physics and Astronomy, University of Delaware, Dept. of Physics and Astronomy, University of Deleware, Dept. of Physics and Astronomy, University of Nevada-Reno, university of Delaware, Contributors, Department of Physics, Astronomy and Geosciences, Towson University, Choice Research Group, Univ of the Sciences in Philadephia, Rutgers Univ, National Institute of Standards and Technology, Department of Chemistry, West Chester University, West Chester, PA 19383, Bucknell University, Towson University, University of Maryland, College of William and Mary, Naval Research Laboratory, Department of Physics, Villanova University, Department of Chemistry, Faculty of Medicine, University of Brescia, Department of Chemistry, State University of New York at Potsdam, Delaware State University DE, NIH Bethesda MD, Wilmington Friends School DE, University Of Rochester NY, Delaware State University, Department of Physics and Astronomy,West Virginia University, The National Energy Technology Laboratory, Non-tenure track professor at research institution, Government Sponsored Laboratory, Research and Development at Industrial Company, Tenure-track Professor at 4 yr college, Department of Physics and Astronomy and Department of Chemistry and Biochemistry, University of Delaware, Biology and Soft Matter Division, Oak Ridge National Laboratory, and Department of Physics and Astronomy, The University of Tennessee, Biology and Soft Matter Division, Oak Ridge National Laboratory, Lehigh Univ, Johns Hopkins Univ, NIST, GMU, GWU, Lock Haven University of PA, Univ of Maryland-Balt County; Center for Nanoscale Materials, Argonne National Laboratory, Department of Chemistry, Northwestern University, Univ of Maryland-Balt County, Pennsylvania State University, BAE Systems, Inc., Nashua, New Hampshire 03061, Department of Physics, West Virginia University, Morgantown, West Virginia, 26506-6315, California State University, Long Beach

  • Cheng Cen

    West Virginia Univ