Terahertz Spectroscopy of Complex Materials

COFFEE_KLATCH · Invited

Abstract

Terahertz time-domain spectroscopy is a powerful tool to investigate complex materials broadly defined. This includes artificial electromagnetic composites such as metamaterials, and correlated electron materials where the interplay between microscopic degrees of freedom leads to phenomena such as superconductivity or metal-insulator transitions. I will discuss our recent results in these areas. Metamaterials are a relatively new type of artificial composite with electromagnetic properties that derive from their sub-wavelength structure. The judicious combination of metamaterials with MEMS technology enables reconfigurable metamaterials where artificial ``atoms'' reorient within unit cells in response to an external stimulus. This is accomplished by fabricating planar arrays of split ring resonators on bimaterial cantilevers designed to bend out of plane in response to a thermal stimulus. In this way we can control the electric and magnetic response of these metamaterials. Vanadium dioxide (VO$_2$) exhibits a metal-insulator transition (MIT) at a temperature (340K) that coincides with a structural phase transition. This leads to the ``chicken and egg'' problem. Is it the structural change or electron correlations that lead to the MIT transition? Uniaxially strained VO$_2$ films have been fabricated to help solve this problem. In unstrained VO$_2$ crystals the insulator to metal transition enables the electrons move freely in three dimensions. Non-contact THz-TDS conductivity measurements of strained samples reveal that the electrons prefer to move in one direction. That is, strain induces a quasi one-dimensional metallic conductivity. These results reveal the utility of terahertz spectroscopy to investigate complex materials and point the way towards future studies of hybrid composites incorporating metamaterials with quantum-based complex matter. Such multi-scale structures may offer complementary benefits where quantum materials confer additional functionality to artificial electromagnetic composites or, conversely, metamaterials serve as a novel tool to facilitate fundamental studies of the electrodynamic response of complex quantum materials.

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Authors

  • Richard D. Averitt

    Trinity College, Department of Physics, Joint appointment in Teacher Education, Wright State University, Graduate School of Education, University of Massachusetts Lowell, Littleton High School, Department of Physics, Boston College, Department of Physics and Applied Physics, University of Massachusetts Lowell, North Carolina State University, University of Massachusetts at Lowell, University of Massachusetts Lowell, Harvard Medical School, Massachusetts General Hospital, Boston, MA, Harvard University, Department of Chemistry University of Massachusetts Amherst, Center for Advanced Materials and Department of Plastics Engineering University of Massachusetts Lowell, Center for Advanced Materials and Department of Physics and Applied Physics University of Massachusetts Lowell, RMD Inc., Watertown MA, UMass Lowell, Lowell MA, Radiation Monitoring Devices Inc., Watertown, MA, USA, University of Massachusetts, Lowell, MA, USA, Argonne National Laboratory, Argonne, IL, USA, ANL, IL, UMass Lowell, Brown University / Department of Chemistry, Sciprint.org, Physics Department, LESIMS Laboratory, Badji Mokhtar University, 23000 Annaba, Algeria, Department of Materials Science and Engineering, Massachusetts Institute of Technology, Physics Department, Boston University