Photoluminescence and ferromagnetism in nitrogen doped ZnO nanoclusters

ORAL

Abstract

Wide-band-gap semiconductor ZnO has been extensively studied for its potential applications in optoelectronic and spintronics. Nitrogen is supposed to be the most promising p-type dopant. We synthesized nitrogen doped ZnO nanoclusters using a third generation sputtering-gas-aggregation cluster source. High-resolution TEM images show nanoclusters sizes are around 12 nm. XRD patterns are identical to bulk ZnO wurtzite structure with the existence of Zn as a minor phase. PL measurements reveal both ultraviolet and green emission which is respectively attributed to recombination of free excitons and deep defect level emissions from intrinsic defects. Unexpected room temperature ferromagnetism is obtained without any magnetic doping elements. It is believed when the doping nitrogen atom is beside zinc atom, one electron in the completely filled d-orbits of Zn possibly jumps to compensate the dangling bond of nitrogen in order to reduce energy. Net spin is established in the left d-orbits of zinc and long range ferromagnetism can be established as described by a bound magnetic polaron model. *supported by DOE-BES (DE-FG02-07ER46386) and DOE-EPSCoR.

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Authors

  • Yufeng Tian

    Department of Physics, University of Idaho, USA, Physics, University of Idaho

  • Ernest Henley

    Green River College, University of British Columbia, Pacific Northwest National Laboratory, BYU-Idaho Dept. of Physics, University of Washington, Applied Physics Technologies, Inc., Montana State University, Universidade Estadual de Campinas, Southern Oregon University, Oregon State University Department of Physics, Oregon State University Department of Chemistry, National Institute of Standards and Technology Center for Neutron Research, Physics Department, Oregon State University, University of Idaho, University of Wyoming, Department of Physics, Montana State University, University of Portland, Idaho State University, WWU, Advanced Light Source, Lawrence Berkeley National Laboratory, Oregon Center for Optics and Department of Physics, University of Oregon, Lewis and Clark, Queen's University, University of Notre Dame, Idaho National Lab, TRIUMF, RCNP, Japan, University of Guelph, Mexico University, St. Mary's University, University of Montreal, Deep River, Dept. of Physics; Montana State University, Dept. of Plant Sciences and Pathology, Dept. of Chem. and Biochem.; Montana State University, Department of Physics, Shandong University, P. R. China, Department of Physics, University of Idaho, USA, Dept. of Physics, Simon Fraser University, Burnaby, BC V5A 1S6 Canada, University of Calgary

  • Ernest Henley

    Green River College, University of British Columbia, Pacific Northwest National Laboratory, BYU-Idaho Dept. of Physics, University of Washington, Applied Physics Technologies, Inc., Montana State University, Universidade Estadual de Campinas, Southern Oregon University, Oregon State University Department of Physics, Oregon State University Department of Chemistry, National Institute of Standards and Technology Center for Neutron Research, Physics Department, Oregon State University, University of Idaho, University of Wyoming, Department of Physics, Montana State University, University of Portland, Idaho State University, WWU, Advanced Light Source, Lawrence Berkeley National Laboratory, Oregon Center for Optics and Department of Physics, University of Oregon, Lewis and Clark, Queen's University, University of Notre Dame, Idaho National Lab, TRIUMF, RCNP, Japan, University of Guelph, Mexico University, St. Mary's University, University of Montreal, Deep River, Dept. of Physics; Montana State University, Dept. of Plant Sciences and Pathology, Dept. of Chem. and Biochem.; Montana State University, Department of Physics, Shandong University, P. R. China, Department of Physics, University of Idaho, USA, Dept. of Physics, Simon Fraser University, Burnaby, BC V5A 1S6 Canada, University of Calgary

  • Ernest Henley

    Green River College, University of British Columbia, Pacific Northwest National Laboratory, BYU-Idaho Dept. of Physics, University of Washington, Applied Physics Technologies, Inc., Montana State University, Universidade Estadual de Campinas, Southern Oregon University, Oregon State University Department of Physics, Oregon State University Department of Chemistry, National Institute of Standards and Technology Center for Neutron Research, Physics Department, Oregon State University, University of Idaho, University of Wyoming, Department of Physics, Montana State University, University of Portland, Idaho State University, WWU, Advanced Light Source, Lawrence Berkeley National Laboratory, Oregon Center for Optics and Department of Physics, University of Oregon, Lewis and Clark, Queen's University, University of Notre Dame, Idaho National Lab, TRIUMF, RCNP, Japan, University of Guelph, Mexico University, St. Mary's University, University of Montreal, Deep River, Dept. of Physics; Montana State University, Dept. of Plant Sciences and Pathology, Dept. of Chem. and Biochem.; Montana State University, Department of Physics, Shandong University, P. R. China, Department of Physics, University of Idaho, USA, Dept. of Physics, Simon Fraser University, Burnaby, BC V5A 1S6 Canada, University of Calgary

  • Ernest Henley

    Green River College, University of British Columbia, Pacific Northwest National Laboratory, BYU-Idaho Dept. of Physics, University of Washington, Applied Physics Technologies, Inc., Montana State University, Universidade Estadual de Campinas, Southern Oregon University, Oregon State University Department of Physics, Oregon State University Department of Chemistry, National Institute of Standards and Technology Center for Neutron Research, Physics Department, Oregon State University, University of Idaho, University of Wyoming, Department of Physics, Montana State University, University of Portland, Idaho State University, WWU, Advanced Light Source, Lawrence Berkeley National Laboratory, Oregon Center for Optics and Department of Physics, University of Oregon, Lewis and Clark, Queen's University, University of Notre Dame, Idaho National Lab, TRIUMF, RCNP, Japan, University of Guelph, Mexico University, St. Mary's University, University of Montreal, Deep River, Dept. of Physics; Montana State University, Dept. of Plant Sciences and Pathology, Dept. of Chem. and Biochem.; Montana State University, Department of Physics, Shandong University, P. R. China, Department of Physics, University of Idaho, USA, Dept. of Physics, Simon Fraser University, Burnaby, BC V5A 1S6 Canada, University of Calgary

  • You Qiang

    Department of Physics, University of Idaho, USA, Physics, University of Idaho