Dispersion and Aggregation of Magnetic Nanoparticles for Nuclear Waste Separation

ORAL

Abstract

A novel method of nuclear waste separation using conjugates of actinide chelators and magnetic nanoparticles (MNPs) is developed. The fast separation can be facilitated by the high magnetic moments of core-shell MNPs. Highly uniform dispersion of MNPs in solutions is required for the efficient conjugation. However, stabilization of well dispersed MNPs hinders fast magnetic collection of the conjugates. To address this dilemma, the dispersion and aggregation of the MNPs has been investigated in both mechanical and chemical approaches. In the mechanical approach, continuous ultrasonic dispersed the MNPs, whereas they re-aggregated after up to 20 minutes treatment. Bead beating method improved the MNPs' suspension time by up to two factors. Nevertheless, the magnetization of MNPs dropped sharply due to the generation of non-magnetic beads' residual. Chemical method using electrolyte and agents with different polarizations had significant effects on the suspension and aggregation of the various sized MNPs. The fine balance of Van de Waals, Brownian forces, magnetic dipole and Coulomb interactions are discussed.

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Authors

  • H. Han

    Physics Department, University of Idaho, Moscow ID 83843

  • Anthony Colaprete

    Triumf, Texas A\&M University, Tel Aviv University, TRIUMF, Simon Fraser University, Dept. of Physics, SFU, BC, Canada, Department of Physics and Astronomy, University of British Columbia, Cavendish Laboratory, University of Cambridge, Department of Physics, Simon Fraser University, University of British Columbia, University of Wisconsin-Madison, Brookhaven National Laboratory, Los Alamos National Laboratory, Department of Molecular Science and Technology, Ajou University, Suwon 443-749, Korea, Department of Physics, Oregon State University, Corvallis, OR 97331-6507, Imago Scientific Instruments Corp., Department of Physics, Simon Fraser University, 8888 University Dr., Burnaby, BC, V5A 1S6 Canada, Linfield College, PNNL, University of Washington, University of Victoria, IUPUI1, Wabash, IUPUI2, Environmental Biotechnology Institute, University of Idaho, Moscow ID 83843, Physics Department, University of Idaho, Moscow ID 83843, Environmental Biotechnology Institute, University of Idaho, Moscow, ID 83844, Physics Department, University of Idaho, Moscow, Idaho 83844, TRIUMF / UBC, 5CSNSM-IN2P3-CNRS, Universit\'e Paris 11, University of Manitoba, Texas A\&M, U. Manitoba, Tel Aviv U., U. British Columbia, Universidad de Pa\'is Vasco, Department of Physics, University of Idaho, Moscow, Idaho 83844-0903, University of Idaho, Boise State University, Idaho State University, NASA Ames Research Center

  • Anthony Colaprete

    Triumf, Texas A\&M University, Tel Aviv University, TRIUMF, Simon Fraser University, Dept. of Physics, SFU, BC, Canada, Department of Physics and Astronomy, University of British Columbia, Cavendish Laboratory, University of Cambridge, Department of Physics, Simon Fraser University, University of British Columbia, University of Wisconsin-Madison, Brookhaven National Laboratory, Los Alamos National Laboratory, Department of Molecular Science and Technology, Ajou University, Suwon 443-749, Korea, Department of Physics, Oregon State University, Corvallis, OR 97331-6507, Imago Scientific Instruments Corp., Department of Physics, Simon Fraser University, 8888 University Dr., Burnaby, BC, V5A 1S6 Canada, Linfield College, PNNL, University of Washington, University of Victoria, IUPUI1, Wabash, IUPUI2, Environmental Biotechnology Institute, University of Idaho, Moscow ID 83843, Physics Department, University of Idaho, Moscow ID 83843, Environmental Biotechnology Institute, University of Idaho, Moscow, ID 83844, Physics Department, University of Idaho, Moscow, Idaho 83844, TRIUMF / UBC, 5CSNSM-IN2P3-CNRS, Universit\'e Paris 11, University of Manitoba, Texas A\&M, U. Manitoba, Tel Aviv U., U. British Columbia, Universidad de Pa\'is Vasco, Department of Physics, University of Idaho, Moscow, Idaho 83844-0903, University of Idaho, Boise State University, Idaho State University, NASA Ames Research Center

  • Anthony Colaprete

    Triumf, Texas A\&M University, Tel Aviv University, TRIUMF, Simon Fraser University, Dept. of Physics, SFU, BC, Canada, Department of Physics and Astronomy, University of British Columbia, Cavendish Laboratory, University of Cambridge, Department of Physics, Simon Fraser University, University of British Columbia, University of Wisconsin-Madison, Brookhaven National Laboratory, Los Alamos National Laboratory, Department of Molecular Science and Technology, Ajou University, Suwon 443-749, Korea, Department of Physics, Oregon State University, Corvallis, OR 97331-6507, Imago Scientific Instruments Corp., Department of Physics, Simon Fraser University, 8888 University Dr., Burnaby, BC, V5A 1S6 Canada, Linfield College, PNNL, University of Washington, University of Victoria, IUPUI1, Wabash, IUPUI2, Environmental Biotechnology Institute, University of Idaho, Moscow ID 83843, Physics Department, University of Idaho, Moscow ID 83843, Environmental Biotechnology Institute, University of Idaho, Moscow, ID 83844, Physics Department, University of Idaho, Moscow, Idaho 83844, TRIUMF / UBC, 5CSNSM-IN2P3-CNRS, Universit\'e Paris 11, University of Manitoba, Texas A\&M, U. Manitoba, Tel Aviv U., U. British Columbia, Universidad de Pa\'is Vasco, Department of Physics, University of Idaho, Moscow, Idaho 83844-0903, University of Idaho, Boise State University, Idaho State University, NASA Ames Research Center

  • Anthony Colaprete

    Triumf, Texas A\&M University, Tel Aviv University, TRIUMF, Simon Fraser University, Dept. of Physics, SFU, BC, Canada, Department of Physics and Astronomy, University of British Columbia, Cavendish Laboratory, University of Cambridge, Department of Physics, Simon Fraser University, University of British Columbia, University of Wisconsin-Madison, Brookhaven National Laboratory, Los Alamos National Laboratory, Department of Molecular Science and Technology, Ajou University, Suwon 443-749, Korea, Department of Physics, Oregon State University, Corvallis, OR 97331-6507, Imago Scientific Instruments Corp., Department of Physics, Simon Fraser University, 8888 University Dr., Burnaby, BC, V5A 1S6 Canada, Linfield College, PNNL, University of Washington, University of Victoria, IUPUI1, Wabash, IUPUI2, Environmental Biotechnology Institute, University of Idaho, Moscow ID 83843, Physics Department, University of Idaho, Moscow ID 83843, Environmental Biotechnology Institute, University of Idaho, Moscow, ID 83844, Physics Department, University of Idaho, Moscow, Idaho 83844, TRIUMF / UBC, 5CSNSM-IN2P3-CNRS, Universit\'e Paris 11, University of Manitoba, Texas A\&M, U. Manitoba, Tel Aviv U., U. British Columbia, Universidad de Pa\'is Vasco, Department of Physics, University of Idaho, Moscow, Idaho 83844-0903, University of Idaho, Boise State University, Idaho State University, NASA Ames Research Center