On the Formation of Luminescent MgZnO Ceramics with the Hexagonal and the Cubic Phase

POSTER

Abstract

Mg(x)Zn(1-x)O is a promising alloy family with UV-tuneable bandgaps, which can have the hexagonal or cubic structure depending on the composition x. ZnO has the hexagonal wurtzite structure and a bandgap of $\sim 3.4$ eV, while MgO has the NaCl cubic structure and a bandgap of $\sim 7.4$ eV. Mg(x)Zn(1-x)O can yield bandgaps spanning the range $3.4$ eV to $7.4$ eV that are achieved via the choice of composition x. We present studies of the optical and material properties of sintered ceramics with two alloy compositions, $x=0.1$ and $x=0.6$, to investigate both the wurtzite and the cubic phases. To study the alloying dynamics, the properties as a function of annealing temperature in the range of 600-1100C were investigated. For the low Mg composition ceramic sample it was found that a threshold temperature around 900C is required in order to initiate the formation of the solid solution of MgZnO with the wurtzite structure. The formation of the high Mg composition ceramic sample was found to have a sequence of phases: initially the alloy formed with the wurtzite structure at around 900C, then a transition into the NaCl cubic structure took place at the high temperature regime. Due to such formation, the cubic phase ceramics inherently include defects within the wurtzite structure.

Authors

  • Leah Bergman

    University of Idaho

  • C. Andreoiu

    University of Washington, Centre for Organic Photonics and Electronics, School of Chemistry and Molecular Biosciences, University of Queensland, Centre for Organic Photonics and Electronics, School of Mathematics and Physics, University of Queensland, Department of Physics, Simon Fraser University, Dalhousie University, Faculty of Mathematics, University of Waterloo, Department of Physics, McMaster University, SLAC National Accelerator Laboratory, Stanford University, Stanford University, IFW-Dresden, Northern Illinois University, University of British Columbia, University of Michigan, Simon Fraser University, Institute for Quantum Computing, University of Waterloo, Washington State University, The University of British Columbia, The Weizmann Institute of Science, Oregon State University, University of Massachusetts Lowell, Aixtron Ltd., Cornell University, TRIUMF, Society of Physics Students, Western Washington University, Department of Physics and Astronomy, Washington State University, University of Portland, Pacific University, University of Idaho, Department of Physics, University of Washington, Emory University, SFU, Arizona State University, Research Centre J\"ulich, University of Victoria, EPM, \'Ecole Polytechnique de Montr\'eal (EPM), Technical U of Denmark, Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, Department of Physics, Portland State University, Portland, OR 97201, Department of Physics, Oregon State University, Corvallis, OR 97331, Department of Physics, Cornell University, Ithaca, NY 14853, Linfield College, Portland State University, University of British Columbia Physics and Astronomy, University of British Columbia Chemistry, Max Planck Institute for Polymer Research, Simon Fraser, Los Alamos National Lab, Los Alamos, McGill University, Los Alamos National Laboratory, University of Cambridge, CSNSM-IN2P3-CNRS, University of Manitobia, Univ. of British Columbia and TRIUMF, Ruprecht-Karls-Universitat and MPI and TRIUMF, Westfaelische Wilhelms-Universitaet, Univ. of Manitoba and TRIUMF, Tenische Universitaet Muenchen and TRIUMF, Simon Fraser Univ. and TRIUMF, University of British Columbia, TRIUMF, Ruprecht-Karls-Universit\"at Heidelberg, Max Planck Institute, TRIUMF, Westf\"alische Wilhelms-Universit\"at, TRIUMF, Johannes Gutenberg-Universit\"at Mainz, Ruprecht-Karls-Universit\"at Heidelberg, Univerity of Manitoba, TRIUMF, Simon Fraser University, TRIUMF, TRIUMF \& University of Manitoba, College of William and Mary, Universidad Autonoma de San Luis Potosi, University of Maryland, University of Manitoba, UBC, Texas A\&M, University of Kentucky, Georgia Institute of Technology, University of Guelph, St. Mary's University

  • C. Andreoiu

    University of Washington, Centre for Organic Photonics and Electronics, School of Chemistry and Molecular Biosciences, University of Queensland, Centre for Organic Photonics and Electronics, School of Mathematics and Physics, University of Queensland, Department of Physics, Simon Fraser University, Dalhousie University, Faculty of Mathematics, University of Waterloo, Department of Physics, McMaster University, SLAC National Accelerator Laboratory, Stanford University, Stanford University, IFW-Dresden, Northern Illinois University, University of British Columbia, University of Michigan, Simon Fraser University, Institute for Quantum Computing, University of Waterloo, Washington State University, The University of British Columbia, The Weizmann Institute of Science, Oregon State University, University of Massachusetts Lowell, Aixtron Ltd., Cornell University, TRIUMF, Society of Physics Students, Western Washington University, Department of Physics and Astronomy, Washington State University, University of Portland, Pacific University, University of Idaho, Department of Physics, University of Washington, Emory University, SFU, Arizona State University, Research Centre J\"ulich, University of Victoria, EPM, \'Ecole Polytechnique de Montr\'eal (EPM), Technical U of Denmark, Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, Department of Physics, Portland State University, Portland, OR 97201, Department of Physics, Oregon State University, Corvallis, OR 97331, Department of Physics, Cornell University, Ithaca, NY 14853, Linfield College, Portland State University, University of British Columbia Physics and Astronomy, University of British Columbia Chemistry, Max Planck Institute for Polymer Research, Simon Fraser, Los Alamos National Lab, Los Alamos, McGill University, Los Alamos National Laboratory, University of Cambridge, CSNSM-IN2P3-CNRS, University of Manitobia, Univ. of British Columbia and TRIUMF, Ruprecht-Karls-Universitat and MPI and TRIUMF, Westfaelische Wilhelms-Universitaet, Univ. of Manitoba and TRIUMF, Tenische Universitaet Muenchen and TRIUMF, Simon Fraser Univ. and TRIUMF, University of British Columbia, TRIUMF, Ruprecht-Karls-Universit\"at Heidelberg, Max Planck Institute, TRIUMF, Westf\"alische Wilhelms-Universit\"at, TRIUMF, Johannes Gutenberg-Universit\"at Mainz, Ruprecht-Karls-Universit\"at Heidelberg, Univerity of Manitoba, TRIUMF, Simon Fraser University, TRIUMF, TRIUMF \& University of Manitoba, College of William and Mary, Universidad Autonoma de San Luis Potosi, University of Maryland, University of Manitoba, UBC, Texas A\&M, University of Kentucky, Georgia Institute of Technology, University of Guelph, St. Mary's University

  • C. Andreoiu

    University of Washington, Centre for Organic Photonics and Electronics, School of Chemistry and Molecular Biosciences, University of Queensland, Centre for Organic Photonics and Electronics, School of Mathematics and Physics, University of Queensland, Department of Physics, Simon Fraser University, Dalhousie University, Faculty of Mathematics, University of Waterloo, Department of Physics, McMaster University, SLAC National Accelerator Laboratory, Stanford University, Stanford University, IFW-Dresden, Northern Illinois University, University of British Columbia, University of Michigan, Simon Fraser University, Institute for Quantum Computing, University of Waterloo, Washington State University, The University of British Columbia, The Weizmann Institute of Science, Oregon State University, University of Massachusetts Lowell, Aixtron Ltd., Cornell University, TRIUMF, Society of Physics Students, Western Washington University, Department of Physics and Astronomy, Washington State University, University of Portland, Pacific University, University of Idaho, Department of Physics, University of Washington, Emory University, SFU, Arizona State University, Research Centre J\"ulich, University of Victoria, EPM, \'Ecole Polytechnique de Montr\'eal (EPM), Technical U of Denmark, Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, Department of Physics, Portland State University, Portland, OR 97201, Department of Physics, Oregon State University, Corvallis, OR 97331, Department of Physics, Cornell University, Ithaca, NY 14853, Linfield College, Portland State University, University of British Columbia Physics and Astronomy, University of British Columbia Chemistry, Max Planck Institute for Polymer Research, Simon Fraser, Los Alamos National Lab, Los Alamos, McGill University, Los Alamos National Laboratory, University of Cambridge, CSNSM-IN2P3-CNRS, University of Manitobia, Univ. of British Columbia and TRIUMF, Ruprecht-Karls-Universitat and MPI and TRIUMF, Westfaelische Wilhelms-Universitaet, Univ. of Manitoba and TRIUMF, Tenische Universitaet Muenchen and TRIUMF, Simon Fraser Univ. and TRIUMF, University of British Columbia, TRIUMF, Ruprecht-Karls-Universit\"at Heidelberg, Max Planck Institute, TRIUMF, Westf\"alische Wilhelms-Universit\"at, TRIUMF, Johannes Gutenberg-Universit\"at Mainz, Ruprecht-Karls-Universit\"at Heidelberg, Univerity of Manitoba, TRIUMF, Simon Fraser University, TRIUMF, TRIUMF \& University of Manitoba, College of William and Mary, Universidad Autonoma de San Luis Potosi, University of Maryland, University of Manitoba, UBC, Texas A\&M, University of Kentucky, Georgia Institute of Technology, University of Guelph, St. Mary's University

  • C. Andreoiu

    University of Washington, Centre for Organic Photonics and Electronics, School of Chemistry and Molecular Biosciences, University of Queensland, Centre for Organic Photonics and Electronics, School of Mathematics and Physics, University of Queensland, Department of Physics, Simon Fraser University, Dalhousie University, Faculty of Mathematics, University of Waterloo, Department of Physics, McMaster University, SLAC National Accelerator Laboratory, Stanford University, Stanford University, IFW-Dresden, Northern Illinois University, University of British Columbia, University of Michigan, Simon Fraser University, Institute for Quantum Computing, University of Waterloo, Washington State University, The University of British Columbia, The Weizmann Institute of Science, Oregon State University, University of Massachusetts Lowell, Aixtron Ltd., Cornell University, TRIUMF, Society of Physics Students, Western Washington University, Department of Physics and Astronomy, Washington State University, University of Portland, Pacific University, University of Idaho, Department of Physics, University of Washington, Emory University, SFU, Arizona State University, Research Centre J\"ulich, University of Victoria, EPM, \'Ecole Polytechnique de Montr\'eal (EPM), Technical U of Denmark, Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, Department of Physics, Portland State University, Portland, OR 97201, Department of Physics, Oregon State University, Corvallis, OR 97331, Department of Physics, Cornell University, Ithaca, NY 14853, Linfield College, Portland State University, University of British Columbia Physics and Astronomy, University of British Columbia Chemistry, Max Planck Institute for Polymer Research, Simon Fraser, Los Alamos National Lab, Los Alamos, McGill University, Los Alamos National Laboratory, University of Cambridge, CSNSM-IN2P3-CNRS, University of Manitobia, Univ. of British Columbia and TRIUMF, Ruprecht-Karls-Universitat and MPI and TRIUMF, Westfaelische Wilhelms-Universitaet, Univ. of Manitoba and TRIUMF, Tenische Universitaet Muenchen and TRIUMF, Simon Fraser Univ. and TRIUMF, University of British Columbia, TRIUMF, Ruprecht-Karls-Universit\"at Heidelberg, Max Planck Institute, TRIUMF, Westf\"alische Wilhelms-Universit\"at, TRIUMF, Johannes Gutenberg-Universit\"at Mainz, Ruprecht-Karls-Universit\"at Heidelberg, Univerity of Manitoba, TRIUMF, Simon Fraser University, TRIUMF, TRIUMF \& University of Manitoba, College of William and Mary, Universidad Autonoma de San Luis Potosi, University of Maryland, University of Manitoba, UBC, Texas A\&M, University of Kentucky, Georgia Institute of Technology, University of Guelph, St. Mary's University

  • C. Andreoiu

    University of Washington, Centre for Organic Photonics and Electronics, School of Chemistry and Molecular Biosciences, University of Queensland, Centre for Organic Photonics and Electronics, School of Mathematics and Physics, University of Queensland, Department of Physics, Simon Fraser University, Dalhousie University, Faculty of Mathematics, University of Waterloo, Department of Physics, McMaster University, SLAC National Accelerator Laboratory, Stanford University, Stanford University, IFW-Dresden, Northern Illinois University, University of British Columbia, University of Michigan, Simon Fraser University, Institute for Quantum Computing, University of Waterloo, Washington State University, The University of British Columbia, The Weizmann Institute of Science, Oregon State University, University of Massachusetts Lowell, Aixtron Ltd., Cornell University, TRIUMF, Society of Physics Students, Western Washington University, Department of Physics and Astronomy, Washington State University, University of Portland, Pacific University, University of Idaho, Department of Physics, University of Washington, Emory University, SFU, Arizona State University, Research Centre J\"ulich, University of Victoria, EPM, \'Ecole Polytechnique de Montr\'eal (EPM), Technical U of Denmark, Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, Department of Physics, Portland State University, Portland, OR 97201, Department of Physics, Oregon State University, Corvallis, OR 97331, Department of Physics, Cornell University, Ithaca, NY 14853, Linfield College, Portland State University, University of British Columbia Physics and Astronomy, University of British Columbia Chemistry, Max Planck Institute for Polymer Research, Simon Fraser, Los Alamos National Lab, Los Alamos, McGill University, Los Alamos National Laboratory, University of Cambridge, CSNSM-IN2P3-CNRS, University of Manitobia, Univ. of British Columbia and TRIUMF, Ruprecht-Karls-Universitat and MPI and TRIUMF, Westfaelische Wilhelms-Universitaet, Univ. of Manitoba and TRIUMF, Tenische Universitaet Muenchen and TRIUMF, Simon Fraser Univ. and TRIUMF, University of British Columbia, TRIUMF, Ruprecht-Karls-Universit\"at Heidelberg, Max Planck Institute, TRIUMF, Westf\"alische Wilhelms-Universit\"at, TRIUMF, Johannes Gutenberg-Universit\"at Mainz, Ruprecht-Karls-Universit\"at Heidelberg, Univerity of Manitoba, TRIUMF, Simon Fraser University, TRIUMF, TRIUMF \& University of Manitoba, College of William and Mary, Universidad Autonoma de San Luis Potosi, University of Maryland, University of Manitoba, UBC, Texas A\&M, University of Kentucky, Georgia Institute of Technology, University of Guelph, St. Mary's University