Fabrication of All-Inorganic Nanocrystal Solids through Matrix Encapsulation of Nanocrystal Arrays

Dale Igram; Dale Igram; Dale Igram; Dale Igram; Dale Igram; Dale Igram; Dale Igram; Dale Igram; Dale Igram

Fabrication of All-Inorganic Nanocrystal Solids through Matrix Encapsulation of Nanocrystal Arrays

ORAL

Abstract

A general strategy for low-temperature processing of colloidal nanocrystals into all-inorganic films is reported. The present methodology goes beyond the traditional ligand-interlinking scheme and relies on encapsulation of morphologically-defined nanocrystal arrays into a matrix of a wide-band gap semiconductor, which preserves optoelectronic properties of individual nanoparticles while rendering the nanocrystal film photoconductive. Fabricated solids exhibit excellent thermal stability, which is attributed to the heteroepitaxial structure of nanocrystal-matrix interfaces, and show compelling light-harvesting performance in prototype solar cells.

Oct. 15, 2011, 8:30 AM – Oct. 15, 2011, 8:45 AM

Authors

Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802
Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802
Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802
Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802
Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802
Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802
Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802
Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802
Dale Igram

Cornell University, Air Force Research Labs, The Center for Photochemical Sciences and Department of Physics, BGSU, Department of Physics, BGSU, Department of Physics and Astronomy, Ball State University, Miami University, Johannes-Gutenberg-Universitat, Mainz, Germany, Martin-Luther-Universitat, Halle, Germany, The Ohio State University, Department of Physics, Columbus, OH 43210, USA, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA, Ohio Northern University, The Ohio State University, Department of Physics, Columbus, OH 43210, Sciprint.org, Ball State University, Department of Physics and Materials Research Institute, Pennsylvania State University, University Park, PA 16802