Electrical and electrochemical characterization of nano-sized LiFePO4 cathode materials synthesized by a lauric acid-based sol--gel method

POSTER

Abstract

We synthesized pure LiFePO$_{4}$ and C-LiFePO$_{4}$ nanoparticles by sol-gel technique. Carbon coating was accomplished by including Lauric acid in the sol-gel precursor solution. Three C-LiFePO$_{4}$ samples of particle sizes 29, 27, 23 nm, were prepared by varying lauric acid concentration in the precursor solution. All the samples were characterized by X-ray diffraction, Raman, conductivity, and electrochemical measurements. The micro-Raman measurements showed two major bands at 1350 and 1590 cm$^{-1}$ respectively (I$_{D}$/I$_{G})$ and the electronic conductivity were found to depend strongly on the amount of surfactant coverage. The 23 nm particle size sample showed minimum (D/G) band ratio and the maximum electrical conductivity among the three samples. The measured value of the capacity for 23 nm sized sample, $\sim $ 170 mAh/g, approached the theoretical capacity limit value for LiFePO$_{4}$

Authors

  • Eric Baer

    Pennsylvania State University, Lincoln University, NHMFL, Brookhaven National Laboratory, University of Wisconsin Oshkosh, The University of Akron, Wayne State University, Physics Department, John Carroll University, Case Western Reserve University, Marietta College, SciPrint.org, High Performance Technologies, Inc., Air Force Institute of Technology, Johannes-Gutenberg-Universit\"at, Mainz, Germany, Martin-Luther-Universit\"at, Halle, Germany, Northwestern University, Youngstown State University, Dept. of Polymer Science, The University of Akron, X-ray Science Division, Argonne National Laboratory, NIST Center for Neutron Research, Electrical Engineering, Youngs. State U., Macromolecular, Case Western Reserve U.

  • Eric Baer

    Pennsylvania State University, Lincoln University, NHMFL, Brookhaven National Laboratory, University of Wisconsin Oshkosh, The University of Akron, Wayne State University, Physics Department, John Carroll University, Case Western Reserve University, Marietta College, SciPrint.org, High Performance Technologies, Inc., Air Force Institute of Technology, Johannes-Gutenberg-Universit\"at, Mainz, Germany, Martin-Luther-Universit\"at, Halle, Germany, Northwestern University, Youngstown State University, Dept. of Polymer Science, The University of Akron, X-ray Science Division, Argonne National Laboratory, NIST Center for Neutron Research, Electrical Engineering, Youngs. State U., Macromolecular, Case Western Reserve U.

  • Eric Baer

    Pennsylvania State University, Lincoln University, NHMFL, Brookhaven National Laboratory, University of Wisconsin Oshkosh, The University of Akron, Wayne State University, Physics Department, John Carroll University, Case Western Reserve University, Marietta College, SciPrint.org, High Performance Technologies, Inc., Air Force Institute of Technology, Johannes-Gutenberg-Universit\"at, Mainz, Germany, Martin-Luther-Universit\"at, Halle, Germany, Northwestern University, Youngstown State University, Dept. of Polymer Science, The University of Akron, X-ray Science Division, Argonne National Laboratory, NIST Center for Neutron Research, Electrical Engineering, Youngs. State U., Macromolecular, Case Western Reserve U.

  • Eric Baer

    Pennsylvania State University, Lincoln University, NHMFL, Brookhaven National Laboratory, University of Wisconsin Oshkosh, The University of Akron, Wayne State University, Physics Department, John Carroll University, Case Western Reserve University, Marietta College, SciPrint.org, High Performance Technologies, Inc., Air Force Institute of Technology, Johannes-Gutenberg-Universit\"at, Mainz, Germany, Martin-Luther-Universit\"at, Halle, Germany, Northwestern University, Youngstown State University, Dept. of Polymer Science, The University of Akron, X-ray Science Division, Argonne National Laboratory, NIST Center for Neutron Research, Electrical Engineering, Youngs. State U., Macromolecular, Case Western Reserve U.

  • Eric Baer

    Pennsylvania State University, Lincoln University, NHMFL, Brookhaven National Laboratory, University of Wisconsin Oshkosh, The University of Akron, Wayne State University, Physics Department, John Carroll University, Case Western Reserve University, Marietta College, SciPrint.org, High Performance Technologies, Inc., Air Force Institute of Technology, Johannes-Gutenberg-Universit\"at, Mainz, Germany, Martin-Luther-Universit\"at, Halle, Germany, Northwestern University, Youngstown State University, Dept. of Polymer Science, The University of Akron, X-ray Science Division, Argonne National Laboratory, NIST Center for Neutron Research, Electrical Engineering, Youngs. State U., Macromolecular, Case Western Reserve U.

  • Eric Baer

    Pennsylvania State University, Lincoln University, NHMFL, Brookhaven National Laboratory, University of Wisconsin Oshkosh, The University of Akron, Wayne State University, Physics Department, John Carroll University, Case Western Reserve University, Marietta College, SciPrint.org, High Performance Technologies, Inc., Air Force Institute of Technology, Johannes-Gutenberg-Universit\"at, Mainz, Germany, Martin-Luther-Universit\"at, Halle, Germany, Northwestern University, Youngstown State University, Dept. of Polymer Science, The University of Akron, X-ray Science Division, Argonne National Laboratory, NIST Center for Neutron Research, Electrical Engineering, Youngs. State U., Macromolecular, Case Western Reserve U.

  • Eric Baer

    Pennsylvania State University, Lincoln University, NHMFL, Brookhaven National Laboratory, University of Wisconsin Oshkosh, The University of Akron, Wayne State University, Physics Department, John Carroll University, Case Western Reserve University, Marietta College, SciPrint.org, High Performance Technologies, Inc., Air Force Institute of Technology, Johannes-Gutenberg-Universit\"at, Mainz, Germany, Martin-Luther-Universit\"at, Halle, Germany, Northwestern University, Youngstown State University, Dept. of Polymer Science, The University of Akron, X-ray Science Division, Argonne National Laboratory, NIST Center for Neutron Research, Electrical Engineering, Youngs. State U., Macromolecular, Case Western Reserve U.