Single Molecule Study of Charge Transfer in 6T-TBrPP-Co Molecular Complex

POSTER

Abstract

When two molecules having tendency to donate or accept electronic charge are put together, charge transfer between the molecules can take place. By a suitable selection of donor and acceptor molecules, it is possible to engineer an entire class of materials having metallic, semiconducting, insulating, or even superconducting properties. Here, we present a low temperature scanning tunneling microscopy and spectroscopy study of single molecule level charge transfer process between $\alpha $-sexithiophene(6T) and TBrPP-Co molecules on a Cu(111) surface. We form molecular clusters composed of both molecular species on Cu(111). The charge transfer between the molecules is directly evident in the tunneling spectroscopy data, which reveals the shift of 6T HOMO towards the surface Fermi level indicating donation of charge from 6T to TBrPP-Co.

Authors

  • Yuan Zhang

    NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, Ohio University, Athens 45701, USA

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville