Molecular Kondo Chain

ORAL

Abstract

Functional molecular systems, for spin-electronic devices, require careful characterizations of magnetic interactions and intermolecular couplings. We present a scanning tunneling microscopic (STM) study of a surface supported molecular system of coupled cobalt ion centers, formed by a surface catalyzed ring coupling reaction. Binding between individual molecular units is confirmed by vertical and lateral manipulations. Spectroscopy (STS) is used to probe Kondo magnetic interaction. Curve fitting of the Kondo spectroscopic feature is used to extract Kondo temperatures, a measure of the interaction energy, for individual magnetic ion sites. Local point spectroscopy and spectroscopic mapping reveal that the magnetic interactions are localized to the cobalt ion sites, and that chain length influences the interaction strength. Analysis of data as a function of chain length and magnetic ion position is combined with density functional theory (DFT) results to argue for antiferromagnetic (AFM) coupling between magnetic centers.

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Authors

  • Andrew R. Dilullo

    Ohio University, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, NQPI, and Dept of Physics \& Astronomy, Ohio University

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville

  • Kurt Baughman

    Center for Nanoscale Materials, Argonne National Lab, Argonne, Illinois, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Ohio University, Los Alamos Nationa Laboratory, National Taiwan University, University of Hamburg, Trinity College, Dublin, Serbian Academy of Sciences and Arts, Institute for Multidisciplinary Research, University of Belgrade, National High Magnetic Field Laboratory, Brookhaven National Laboratory, The University of Akron, NQPI, Physics and Astronomy Dept., Ohio University, GNS \& MANA Satellite, CEMES, CNRS, IMRE, A*STAR, Nanoscale and Quantum Phenomena Institute (NQPI), Physics and Astronomy Dept., Ohio University, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH 45701, CEMES, CNRS, Toulouse, France, Nanoscale and Quantum Phenomena Institute, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI, and Department of Physics \& Astronomy, Ohio University, Athens, OH, NQPI Dept of Physics and astronomy Ohio University, Naval Research Labs, Washington DC 20375, John Carroll University, Lawrence Livermore National Laboratory, The Ohio State University Department of Physics, Nanoscale and Quantum Phenomena Institute, Department of Physics and Astronomy, Ohio University, Athens, Ohio, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, National High Magnetic Field Laboratory, Tallahassee, University of Wisconsin Oshkosh, Wittenberg University, NQPI, Ohio University; CNM Argonne National Laboratory, APS, CNM, Argonne National Laboratory, Ohio University, Athens 45701, USA, None, Dept. of Physics, Hiram College, Physics Department, Cleveland State University, Flash Center for Computational Science, University of Chicago, Center for Energy Research, University of California San Diego; Lawrence Livermore National Laboratory, Ohio Northern University, Ohio University Zanesville