Optical Absorption and Luminescence Studies of Sn Doped ZnO Single Crystals

ORAL

Abstract

High quality undoped and Tin doped Zinc Oxide (ZnO:Sn) single crystals were grown by the chemical vapor transport (CVT) method and studied by optical absorption and thermo-luminescence (TL) spectroscopies. Significant changes in TL and absorption spectra were induced by Sn doping. By varying Sn concentration, the color of the samples has changed from colorless to dark blue. Optical absorption measurements revealed no change in the band gap and indicated that the dark blue color is due to a broad peak beyond 600 nm. Following our recent approach in applying low temperature TL in measuring donor ionization energies in ZnO, inspection of TL glow spectroscopy showed a change in the donor ionization energy and density after doping.

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Authors

  • Micah Haseman

    Bowling Green State University

  • Brian Knauf

    Electro-Optics Graduate Program, University of Dayton, Dayton, Ohio 45469, Bowling Green State University, Washington State University, Nuclear Radiation Center, Washington State University, Electro-Optics Program, University of Dayton, Dayton, OH 45469, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ, Department of Physics, Arizona State University, Tempe, AZ, Nano-C, Inc., U. S. Army Research Laboratory, Professor, TA, None

  • Brian Knauf

    Electro-Optics Graduate Program, University of Dayton, Dayton, Ohio 45469, Bowling Green State University, Washington State University, Nuclear Radiation Center, Washington State University, Electro-Optics Program, University of Dayton, Dayton, OH 45469, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ, Department of Physics, Arizona State University, Tempe, AZ, Nano-C, Inc., U. S. Army Research Laboratory, Professor, TA, None

  • Brian Knauf

    Electro-Optics Graduate Program, University of Dayton, Dayton, Ohio 45469, Bowling Green State University, Washington State University, Nuclear Radiation Center, Washington State University, Electro-Optics Program, University of Dayton, Dayton, OH 45469, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ, Department of Physics, Arizona State University, Tempe, AZ, Nano-C, Inc., U. S. Army Research Laboratory, Professor, TA, None

  • Brian Knauf

    Electro-Optics Graduate Program, University of Dayton, Dayton, Ohio 45469, Bowling Green State University, Washington State University, Nuclear Radiation Center, Washington State University, Electro-Optics Program, University of Dayton, Dayton, OH 45469, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ, Department of Physics, Arizona State University, Tempe, AZ, Nano-C, Inc., U. S. Army Research Laboratory, Professor, TA, None