Physisorption strain in CVD graphene on copper substrates

ORAL

Abstract

Strain and morphology of CVD (chemical vapor deposition) graphene layers grown on Cu substrates are studied by Raman spectroscopy and scanning tunneling microscopy (STM). We find that CVD graphene on Cu surfaces are subject to strain which depends on the orientation of the underlying Cu surfaces. The strain is compressive on Cu (111) surface. For graphene grown on Cu (100) surface, the strain is highly nonuniform and includes both compressive and tensile components. Molecular dynamics (MD) simulations show that the compressive strain in graphene on Cu (111) is on the order of 0.5 percent expressed through the presence of hexagonal superstructures and highly compressed domain walls. MD simulations of graphene on Cu (100) show highly nonuniform strain patterns including linear superstructures, consistent with the patterns seen in STM. For graphene grown on Cu foil the strain is partially released after graphene is removed from Cu surfaces and transferred onto oxidized Si substrate.

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Authors

  • Rui He

    Univ of Northern Iowa, University of Northern Iowa

  • John Gaddy

    University of Southern California, University of Chicago, University of Toronto, Argonne National Laboratory, Illinois Institute of Technology, University of Northern Iowa, Universite Aix-Marseille 1, Universite Montpellier 2, University of Missouri, University of Missouri, Department of Physics and Astronomy and the Missouri Research Reactor, University of Missouri, Department of Physics and Astronomy, University of Missouri, the Missouri Research Reactor, Columbia Univ, Univ of Northern Iowa, University of Charleston, NASA Goddard Space Flight Center, Iowa State University, University of Colorado, NOAO, University of Toledo, University of Massachusetts, Smith College, Observatory of Bordeaux, Spitzer Science Center, University of Chile, SAO

  • John Gaddy

    University of Southern California, University of Chicago, University of Toronto, Argonne National Laboratory, Illinois Institute of Technology, University of Northern Iowa, Universite Aix-Marseille 1, Universite Montpellier 2, University of Missouri, University of Missouri, Department of Physics and Astronomy and the Missouri Research Reactor, University of Missouri, Department of Physics and Astronomy, University of Missouri, the Missouri Research Reactor, Columbia Univ, Univ of Northern Iowa, University of Charleston, NASA Goddard Space Flight Center, Iowa State University, University of Colorado, NOAO, University of Toledo, University of Massachusetts, Smith College, Observatory of Bordeaux, Spitzer Science Center, University of Chile, SAO

  • John Gaddy

    University of Southern California, University of Chicago, University of Toronto, Argonne National Laboratory, Illinois Institute of Technology, University of Northern Iowa, Universite Aix-Marseille 1, Universite Montpellier 2, University of Missouri, University of Missouri, Department of Physics and Astronomy and the Missouri Research Reactor, University of Missouri, Department of Physics and Astronomy, University of Missouri, the Missouri Research Reactor, Columbia Univ, Univ of Northern Iowa, University of Charleston, NASA Goddard Space Flight Center, Iowa State University, University of Colorado, NOAO, University of Toledo, University of Massachusetts, Smith College, Observatory of Bordeaux, Spitzer Science Center, University of Chile, SAO

  • John Gaddy

    University of Southern California, University of Chicago, University of Toronto, Argonne National Laboratory, Illinois Institute of Technology, University of Northern Iowa, Universite Aix-Marseille 1, Universite Montpellier 2, University of Missouri, University of Missouri, Department of Physics and Astronomy and the Missouri Research Reactor, University of Missouri, Department of Physics and Astronomy, University of Missouri, the Missouri Research Reactor, Columbia Univ, Univ of Northern Iowa, University of Charleston, NASA Goddard Space Flight Center, Iowa State University, University of Colorado, NOAO, University of Toledo, University of Massachusetts, Smith College, Observatory of Bordeaux, Spitzer Science Center, University of Chile, SAO

  • John Gaddy

    University of Southern California, University of Chicago, University of Toronto, Argonne National Laboratory, Illinois Institute of Technology, University of Northern Iowa, Universite Aix-Marseille 1, Universite Montpellier 2, University of Missouri, University of Missouri, Department of Physics and Astronomy and the Missouri Research Reactor, University of Missouri, Department of Physics and Astronomy, University of Missouri, the Missouri Research Reactor, Columbia Univ, Univ of Northern Iowa, University of Charleston, NASA Goddard Space Flight Center, Iowa State University, University of Colorado, NOAO, University of Toledo, University of Massachusetts, Smith College, Observatory of Bordeaux, Spitzer Science Center, University of Chile, SAO

  • John Gaddy

    University of Southern California, University of Chicago, University of Toronto, Argonne National Laboratory, Illinois Institute of Technology, University of Northern Iowa, Universite Aix-Marseille 1, Universite Montpellier 2, University of Missouri, University of Missouri, Department of Physics and Astronomy and the Missouri Research Reactor, University of Missouri, Department of Physics and Astronomy, University of Missouri, the Missouri Research Reactor, Columbia Univ, Univ of Northern Iowa, University of Charleston, NASA Goddard Space Flight Center, Iowa State University, University of Colorado, NOAO, University of Toledo, University of Massachusetts, Smith College, Observatory of Bordeaux, Spitzer Science Center, University of Chile, SAO

  • John Gaddy

    University of Southern California, University of Chicago, University of Toronto, Argonne National Laboratory, Illinois Institute of Technology, University of Northern Iowa, Universite Aix-Marseille 1, Universite Montpellier 2, University of Missouri, University of Missouri, Department of Physics and Astronomy and the Missouri Research Reactor, University of Missouri, Department of Physics and Astronomy, University of Missouri, the Missouri Research Reactor, Columbia Univ, Univ of Northern Iowa, University of Charleston, NASA Goddard Space Flight Center, Iowa State University, University of Colorado, NOAO, University of Toledo, University of Massachusetts, Smith College, Observatory of Bordeaux, Spitzer Science Center, University of Chile, SAO