Neutron scattering studies of glassy solid state Li electrolytes

POSTER

Abstract

We present characterizations, performed using two different neutron scattering techniques, on superionic materials that are good candidates for use as solid state electrolytes in next generation Li$^{+}$ ion batteries. The materials are glassy in nature and composed of a complex network of the following sub-units: Li$_{2}$O, Li$_{2}$SO$_{4}$, and 2NH$_{4}$H$_{2}$PO$_{2}$. This disordered structure is integral to its function in that it promotes Li$^{+}$ ion conduction while suppressing electron conduction, the necessary qualities of a good Li$^{+}$ electrolyte. We have implemented neutron diffraction to study the formation of crystallites upon heating of the material above 400$^{\circ}$ C. The crystallite formation is understood to be detrimental to the Li$^{+}$ ion mobility and, hence, is identified with a diminished performance in devices that require heating in their fabrication process. We have also used a triple-axis spectrometer to begin to separate out the diffuse scattering that results from the disordered structure of the material from the diffuse scattering that results from dynamic processes that occur in it. This is done by a comparative study of the energy resolved versus energy integrated scattering over the full available q-range.

Authors

  • Leo Zella

    New Mexico State University and the University of Missouri Research Reactor

  • Jatinder Kumar

    Harvard U., Baker University, Bejing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Northrop Grumman, Baltimore, MD, University of Kansas Dept. of Physics \& Astronomy, Kansas State University, Department of Chemistry, College of Materials Science \& Engineering, Sichuan University, China, Illinois State University, Mullard Space Science Laboratory, University College of London, Holmbury St. Mary, United Kingdom, Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, CO, United States, Weizmann Institute of Science, Rehovot, Israel, Monmouth College, Missouri State University, Birla Institute of Technology and Science, University of Illinois at Urbana Champaign, Ames Laboratory. Department of Physics and Astronomy, Iowa State University, Siena College, \'Ecole Polytechnique F\'ed\'erale de Lausanne, Switzerland, Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Kansas State University, Purdue University, Princeton University, Oklahoma State University, University of Chicago, University of Iowa, University of Kansas, University of Kansas and University of Iowa

  • Jatinder Kumar

    Harvard U., Baker University, Bejing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Northrop Grumman, Baltimore, MD, University of Kansas Dept. of Physics \& Astronomy, Kansas State University, Department of Chemistry, College of Materials Science \& Engineering, Sichuan University, China, Illinois State University, Mullard Space Science Laboratory, University College of London, Holmbury St. Mary, United Kingdom, Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, CO, United States, Weizmann Institute of Science, Rehovot, Israel, Monmouth College, Missouri State University, Birla Institute of Technology and Science, University of Illinois at Urbana Champaign, Ames Laboratory. Department of Physics and Astronomy, Iowa State University, Siena College, \'Ecole Polytechnique F\'ed\'erale de Lausanne, Switzerland, Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Kansas State University, Purdue University, Princeton University, Oklahoma State University, University of Chicago, University of Iowa, University of Kansas, University of Kansas and University of Iowa

  • Jatinder Kumar

    Harvard U., Baker University, Bejing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Northrop Grumman, Baltimore, MD, University of Kansas Dept. of Physics \& Astronomy, Kansas State University, Department of Chemistry, College of Materials Science \& Engineering, Sichuan University, China, Illinois State University, Mullard Space Science Laboratory, University College of London, Holmbury St. Mary, United Kingdom, Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, CO, United States, Weizmann Institute of Science, Rehovot, Israel, Monmouth College, Missouri State University, Birla Institute of Technology and Science, University of Illinois at Urbana Champaign, Ames Laboratory. Department of Physics and Astronomy, Iowa State University, Siena College, \'Ecole Polytechnique F\'ed\'erale de Lausanne, Switzerland, Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Kansas State University, Purdue University, Princeton University, Oklahoma State University, University of Chicago, University of Iowa, University of Kansas, University of Kansas and University of Iowa

  • Jatinder Kumar

    Harvard U., Baker University, Bejing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Northrop Grumman, Baltimore, MD, University of Kansas Dept. of Physics \& Astronomy, Kansas State University, Department of Chemistry, College of Materials Science \& Engineering, Sichuan University, China, Illinois State University, Mullard Space Science Laboratory, University College of London, Holmbury St. Mary, United Kingdom, Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, CO, United States, Weizmann Institute of Science, Rehovot, Israel, Monmouth College, Missouri State University, Birla Institute of Technology and Science, University of Illinois at Urbana Champaign, Ames Laboratory. Department of Physics and Astronomy, Iowa State University, Siena College, \'Ecole Polytechnique F\'ed\'erale de Lausanne, Switzerland, Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Kansas State University, Purdue University, Princeton University, Oklahoma State University, University of Chicago, University of Iowa, University of Kansas, University of Kansas and University of Iowa

  • Tom Heitmann

    University of Missouri Research Reactor